Real-Time Probing of Intramolecular Vibrational Energy Redistribution and Intermolecular Vibrational Energy Transfer of Selectively Excited CH2I2Molecules in Solution†

2001 ◽  
Vol 105 (21) ◽  
pp. 5071-5080 ◽  
Author(s):  
Ales Charvat ◽  
Jens Aβmann ◽  
Bernd Abel ◽  
Dirk Schwarzer
Keyword(s):  
Energy Transfer ◽  
Real Time ◽  
Vibrational Energy ◽  
Vibrational Energy Transfer ◽  
Energy Redistribution ◽  
Intramolecular Vibrational Energy Redistribution

Understanding the intramolecular vibrational energy transfer and structural dynamics of anionic ligands in a photo-catalytic CO2 reduction catalyst

2019 ◽  
Vol 21 (41) ◽  
pp. 23026-23035 ◽  
Author(s):  
Qianchen Liu ◽  
Yutong Zhang ◽  
Qi Zhang ◽  
Qianshun Wei ◽  
Dexia Zhou ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Structural Dynamics ◽  
Vibrational Energy ◽  
Co2 Reduction ◽  
Catalytic Process ◽  
Vibrational Energy Transfer ◽  
Energy Redistribution ◽  
Intramolecular Vibrational Energy Redistribution ◽  
Anionic Ligands

The knowledge of intramolecular vibrational energy redistribution (IVR) and structural dynamics of rhenium photo-catalysts is essential for understanding the mechanism of the photo-catalytic process of CO2 reduction.

scholarly journals Role of electron in intramolecular vibrational energy redistribution: a simulation of time- and frequency-resolved CARS spectrum

RSC Advances ◽  
2019 ◽  
Vol 9 (45) ◽  
pp. 26030-26036 ◽  
Author(s):  
Zanhao Wang ◽  
Honglin Wu ◽  
Xiaosong Liu ◽  
Yunfei Song ◽  
Yanqiang Yang
Keyword(s):  
Energy Transfer ◽  
Vibrational Energy ◽  
Energy Transfer Efficiency ◽  
Transfer Efficiency ◽  
Vibrational Energy Transfer ◽  
Energy Redistribution ◽  
Intramolecular Vibrational Energy Redistribution ◽  
Mediator Role

The electron plays a mediator role in the IVR process and significantly increases the vibrational energy transfer efficiency.

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