Visible to Near-Infrared Ultrafast Spectroscopy of a Quasi-One-Dimensional Halogen-Bridged Mixed-Valence Metal Complex [Pt(en)2][Pt(en)2Cl2](ClO4)4

2002 ◽  
Vol 106 (4) ◽  
pp. 581-588 ◽  
Author(s):  
Atsushi Sugita ◽  
Tomoshige Furuhi ◽  
Masahiro Yamashita ◽  
Takayoshi Kobayashi
Keyword(s):  
Metal Complex ◽  
Ultrafast Spectroscopy ◽  
Near Infrared ◽  
Mixed Valence ◽  
One Dimensional

A one-dimensional chloride-bridged PtII/PtIVmixed-valence complex with a 4-[(4-hydroxyphenyl)diazenyl]benzenesulfonate counter-ion

2015 ◽  
Vol 71 (12) ◽  
pp. 1033-1036 ◽  
Author(s):  
Nobuyuki Matsushita ◽  
Ayako Taira
Keyword(s):  
Valence State ◽  
Title Compound ◽  
Linear Chain ◽  
Mixed Valence ◽  
Chain Structure ◽  
Structural Parameter ◽  
One Dimensional ◽  
Square Planar ◽  
Cl Atoms ◽  
Linear Chain Structure

The title compound,catena-poly[[[bis(ethylenediamine-κ2N,N′)platinum(II)]- μ-chlorido-[bis(ethylenediamine)platinum(IV)]-μ-chlorido] tetrakis{4-[(4-hydroxyphenyl)diazenyl]benzenesulfonate} dihydrate], {[PtIIPtIVCl2(C2H8N2)4](HOC6H4N=NC6H4SO3)4·2H2O}n, has a linear chain structure composed of square-planar [Pt(en)2]2+(en is ethylenediamine) and elongated octahedraltrans-[PtCl2(en)2]2+cations stacked alternately, bridged by Cl atoms, along thebaxis. The Pt atoms are located on an inversion centre, while the Cl atoms are disordered over two sites and form a zigzag ...Cl—PtIV—Cl...PtII... chain, with a PtIV—Cl bond length of 2.3140 (14) Å, an interatomic PtII...Cl distance of 3.5969 (15) Å and a PtIV—Cl...PtIIangle of 170.66 (6)°. The structural parameter indicating the mixed-valence state of the Pt atom, expressed by δ = (PtIV—Cl)/(PtII...Cl), is 0.643.

The length controllable synthesis and near-infrared photoluminescence of one-dimensional ternary Cu4Bi4S9 semiconductor nanobelts

2014 ◽  
Vol 49 ◽  
pp. 180-186 ◽  
Author(s):  
Jing Li ◽  
Xiaoxu wang ◽  
Ruibin Liu ◽  
Lijie shi ◽  
Muhammad Arshad Kamran ◽  
...  
Keyword(s):  
Near Infrared ◽  
Controllable Synthesis ◽  
One Dimensional

Orthogonal electronic coupling in multicentre arylamine mixed-valence compounds based on a dibenzofulvene–thiophene conjugated bridge

2017 ◽  
Vol 53 (64) ◽  
pp. 8960-8963 ◽  
Author(s):  
A. Beneduci ◽  
G. A. Corrente ◽  
E. Fabiano ◽  
V. Maltese ◽  
S. Cospito ◽  
...  
Keyword(s):  
Near Infrared ◽  
Mixed Valence ◽  
Infrared Region ◽  
Optical Modulation ◽  
Electronic Coupling ◽  
Voltage Dependent ◽  
Near Infrared Region ◽  
Mixed Valence Compounds

Novel H-shaped tetrarylamine mixed valence compounds showing orthogonal electronic coupling generate voltage-dependent electro-optical modulation in the near infrared region.

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