Dependence of the Photocurrent Conversion Efficiency of Dye-Sensitized Solar Cells on the Incident Light Intensity

2000 ◽  
Vol 104 (48) ◽  
pp. 11484-11488 ◽  
Author(s):  
T. Trupke ◽  
P. Würfel ◽  
I. Uhlendorf
Author(s):  
Eli Danladi ◽  
Jamila Tasiu ◽  
Lucky Endas

Surface plasmon resonance is the effect of electron oscillation in a structure stimulated by incident light. When noble materials such as Ag, Au or Cu are added into the titania (compact or mesoporous) structure of the sensitized solar cell, the plasmonic effect of such materials will result an improved performance of the device. Placing AgNPs at different position will produce a variety of result. In this work the systematic design and formation of plasmonic dye sensitized solar cells (DSSCs) by integrating Ag NPs nanoparticles (NPs) in two distinct configurations; on the c-TiO2 and on m-TiO2 were reported. The power conversion efficiency (PCE), Jsc and Voc of the reference device shows a value of 0.36 %, 1.89 mAcm-2 and 0.45 V. Upon introduction of AgNPs on the c-TiO2, a PCE of 0.64 %, Jsc of 2.53 mAcm-2 and Voc of 0.46 V were recorded, which improved the PCE ~ 63.90 % over that of the prestine device. When AgNPs is introduced on the m-TiO2, a PCE of 0.71 %, Jsc of 2.83 mAcm-2 and Voc of 0.46 V were obtained which which results to increase in power conversion efficiency (PCE) from 0.36 % to 0.71 %, demonstrating ~1.97 time’s enhancement, compared with the reference device without the metal NPs. The improvement is attributed to an increase in photocurrent density due to enhanced light harvesting by silver nanoparticles.


Nanoscale ◽  
2014 ◽  
Vol 6 (23) ◽  
pp. 14433-14440 ◽  
Author(s):  
Sheng-qi Guo ◽  
Tian-zeng Jing ◽  
Xiao Zhang ◽  
Xiao-bing Yang ◽  
Zhi-hao Yuan ◽  
...  

In this work, we report the synthesis of mesoporous Bi2S3 nanorods under hydrothermal conditions without additives, and investigated their catalytic activities as the CE in DSCs by I–V curves and tested conversion efficiency.


2021 ◽  
Vol 11 (3) ◽  
pp. 674-678
Author(s):  
Shibing Zou ◽  
Lingting Song ◽  
Junhong Duan ◽  
Le Huang ◽  
Weiqing Liu ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (87) ◽  
pp. 83802-83807 ◽  
Author(s):  
Yu Hou ◽  
Shuang Yang ◽  
Chunzhong Li ◽  
Huijun Zhao ◽  
Hua Gui Yang

An energy conversion efficiency of 8.31% is reached by using a cemented photoanode for dye-sensitized solar cells, attaining a 31.1% improvement over the standard Degussa P25 sample.


2017 ◽  
Vol 19 (18) ◽  
pp. 11187-11196 ◽  
Author(s):  
Pooya Tahay ◽  
Meisam Babapour Gol Afshani ◽  
Ali Alavi ◽  
Zahra Parsa ◽  
Nasser Safari

Photocurrent efficiency measurements and other experimental results demonstrate that the best TiO2 nanoparticle size depends on the intrinsic properties of the dye and the best size changes with dye type.


2015 ◽  
Vol 19 (01-03) ◽  
pp. 175-191 ◽  
Author(s):  
Ganesh D. Sharma ◽  
Galateia E. Zervaki ◽  
Kalliopi Ladomenou ◽  
Emmanuel N. Koukaras ◽  
Panagiotis P. Angaridis ◽  
...  

Two porphyrin dyads with the donor-π-acceptor molecular architecture, namely ( ZnP )-[triazine-gly]-( H 2 PCOOH ) and ( ZnP )-[triazine-Npip]-( H 2 PCOOH ), which consist of a zinc-metalated porphyrin unit and a free-base porphyrin unit covalently linked at their peripheries to a central triazine group, substituted either by a glycine in the former or a N-piperidine group in the latter, have been synthesized via consecutive amination substitution reactions of cyanuric chloride. The UV-vis absorption spectra and cyclic-voltammetry measurements of the two dyads, as well as theoretical calculations based on Density Functional Theory, suggest that they have suitable frontier orbital energy levels for use as sensitizers in dye-sensitized solar cells. Dye-sensitized solar cells based on ( ZnP )-[triazine-gly]-( H 2 PCOOH ) and ( ZnP )-[triazine-Npip]-( H 2 PCOOH ) have been fabricated, and they were found to exhibit power conversion efficiency values of 5.44 and 4.15%, respectively. Photovoltaic measurements (J–V curves) and incident photon to current conversion efficiency spectra of the two solar cells suggest that the higher power conversion efficiency value of the former solar cell is a result of its enhanced short circuit current, open circuit voltage, and fill factor values, as well as higher dye loading. This is ascribed to the existence of two carboxylic acid anchoring groups in ( ZnP )-[triazine-gly]-( H 2 PCOOH ), compared to one carboxylic acid group in ( ZnP )-[triazine-Npip]-( H 2 PCOOH ), which leads to a more effective binding onto the TiO 2 photoanode. Electrochemical impedance spectra show evidence that the ( ZnP )-[triazine-gly]-( H 2 PCOOH ) based solar cell exhibits a longer electron lifetime and more effective suppression of charge recombination reactions between the injected electrons and electrolyte.


2012 ◽  
Vol 629 ◽  
pp. 332-338 ◽  
Author(s):  
Zhi Hua Tian ◽  
Jian Xi Yao ◽  
Mi Na Guli

TiO2 films with three-dimensional web-like structure have been prepared by the photo polymerization-induced phase separation method (PIPS). Scanning electron microscopy and X-ray diffraction were used to characterize the as-prepared TiO2 films. The results showed that the film texture could be tuned by changing the composition of the precursor solution. The TiO2 film with web-like structure exhibited high photocatalytic activity for the degradation of methylene blue (MB) dye. The as-prepared films were used as the photo-anodes in dye-sensitized solar cells (DSCs). The photoelectric conversion efficiency of the DSCs was significantly enhanced by changing the POGTA/TTB in the precursor solution. Because of the increased dye adsorption active sites and efficient electron transport in the TiO2 anode film, a photoelectric conversion efficiency of 3.015% was obtained.


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