Fe(II)-Catalyzed Imidation of Allyl Sulfides and Subsequent [2,3]-Sigmatropic Rearrangement. Preparation of α-BranchedN-tert-Butyloxycarbonyl (Boc)-ProtectedN-Allylamines

2000 ◽  
Vol 65 (8) ◽  
pp. 2358-2367 ◽  
Author(s):  
Thorsten Bach ◽  
Christina Körber
Keyword(s):  
Sigmatropic Rearrangement ◽  
Allyl Sulfides

Catalyst-Free Imidation of Allyl Sulfides with Chloramine-T and Subsequent [2,3]-Sigmatropic Rearrangement

2012 ◽  
Vol 30 (9) ◽  
pp. 2029-2035 ◽  
Author(s):  
Yubo Jiang ◽  
Fanyang Mo ◽  
Di Qiu ◽  
Chunxiang Kuang ◽  
Yan Zhang ◽  
...  
Keyword(s):  
Sigmatropic Rearrangement ◽  
Catalyst Free ◽  
Chloramine T ◽  
Allyl Sulfides

Catalytic Asymmetric [2,3]-Sigmatropic Rearrangement of Sulfur Ylides Generated from Copper(I) Carbenoids and Allyl Sulfides

2002 ◽  
Vol 67 (16) ◽  
pp. 5621-5625 ◽  
Author(s):  
Xiaomei Zhang ◽  
Zhaohui Qu ◽  
Zhihua Ma ◽  
Weifeng Shi ◽  
Xianglin Jin ◽  
...  
Keyword(s):  
Sigmatropic Rearrangement ◽  
Sulfur Ylides ◽  
Catalytic Asymmetric ◽  
Allyl Sulfides

scholarly journals Catalytic Asymmetric [2,3]-Sigmatropic Rearrangement of Sulfur Ylides Generated from Copper(I) Carbenoids and Allyl Sulfides.

ChemInform ◽  
2003 ◽  
Vol 34 (2) ◽  
Author(s):  
Xiaomei Zhang ◽  
Zhaohui Qu ◽  
Zhihua Ma ◽  
Weifeng Shi ◽  
Xianglin Jin ◽  
...  
Keyword(s):  
Sigmatropic Rearrangement ◽  
Sulfur Ylides ◽  
Catalytic Asymmetric ◽  
Allyl Sulfides

Garlic-Derived Allyl Sulfides in Cancer Therapy

2014 ◽  
Vol 14 (6) ◽  
pp. 793-799 ◽  
Author(s):  
Hai-Xia Cao ◽  
Ke-Xiang Zhu ◽  
Jian-Gao Fan ◽  
Liang Qiao
Keyword(s):  
Cancer Therapy ◽  
Allyl Sulfides

scholarly journals Copper-Catalyzed Synthesis of Axially Chiral Biaryls with Diaryliodonium Salts as Arylation Reagents

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3223
Author(s):  
Ji-Wei Zhang ◽  
Shao-Hua Xiang ◽  
Shaoyu Li ◽  
Bin Tan
Keyword(s):  
Amino Alcohols ◽  
Sigmatropic Rearrangement ◽  
Synthetic Route ◽  
Mild Conditions ◽  
Good Substrate ◽  
Diaryliodonium Salts ◽  
Axially Chiral

NOBIN and BINAM derivatives harboring biaryl frameworks are recognized as a class of important atropisomers with versatile applications. Here, we present an efficient synthetic route to access such compounds through copper-catalyzed domino arylation of N-arylhydroxylamines or N-arylhydrazines with diaryliodonium salts and [3,3]-sigmatropic rearrangement. This reaction features mild conditions, good substrate compatibility, and excellent efficiency. The practicality of this protocol was further extended by the synthesis of biaryl amino alcohols.

An Umpolung Oxa-[2,3] Sigmatropic Rearrangement Employing Arynes for the Synthesis of Functionalized Enol Ethers

2021 ◽  
Author(s):  
Rahul N. Gaykar ◽  
Malini George ◽  
Avishek Guin ◽  
Subrata Bhattacharjee ◽  
Akkattu T. Biju
Keyword(s):  
Sigmatropic Rearrangement ◽  
Enol Ethers
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