Onium Transfer Reaction of (β,β-Dialkylvinyl)(phenyl)iodonium Tetrafluoroborates via an Alkylidene Carbene Pathway:  Synthesis of Group 15 Alkenyl(triphenyl)- and Group 16 Alkenyl(diphenyl)onium Salts

1999 ◽  
Vol 64 (23) ◽  
pp. 8563-8567 ◽  
Author(s):  
Masahito Ochiai ◽  
Takuya Sueda ◽  
Rie Noda ◽  
Motoo Shiro
Keyword(s):  
Transfer Reaction ◽  
Onium Salts ◽  
Group 15 ◽  
Alkylidene Carbene ◽  
Group 16

Synthesis of 1-Alkynyl(diphenyl)onium Salts of Group 16 Elements via Heteroatom Transfer Reaction of 1-Alkynyl(phenyl)-λ3-iodanes.

ChemInform ◽  
2003 ◽  
Vol 34 (36) ◽  
Author(s):  
Masahito Ochiai ◽  
Takema Nagaoka ◽  
Takuya Sueda ◽  
Jie Yan ◽  
Da-Wei Chen ◽  
...  
Keyword(s):  
Transfer Reaction ◽  
Onium Salts ◽  
Group 16

Synthesis of 1-alkynyl(diphenyl)onium salts of group 16 elements via heteroatom transfer reaction of 1-alkynyl(phenyl)-λ3-iodanes

2003 ◽  
Vol 1 (9) ◽  
pp. 1517-1521 ◽  
Author(s):  
Masahito Ochiai ◽  
Takema Nagaoka ◽  
Takuya Sueda ◽  
Jie Yan ◽  
Da-Wei Chen ◽  
...  
Keyword(s):  
Transfer Reaction ◽  
Onium Salts ◽  
Group 16

ChemInform Abstract: Metallacycles with Group 15 and Group 16 Ligands

ChemInform ◽  
2010 ◽  
Vol 28 (15) ◽  
pp. no-no
Author(s):  
J. D. WOOLLINS
Keyword(s):  
Group 15 ◽  
Group 16

ChemInform Abstract: Organomagnesium Group 15- and Organomagnesium Group 16-Bonded Complexes

ChemInform ◽  
2009 ◽  
Vol 40 (40) ◽  
Author(s):  
Katherine L. Hull ◽  
Kenneth W. Henderson
Keyword(s):  
Group 15 ◽  
Group 16 ◽  
Bonded Complexes

scholarly journals On the Importance of Pnictogen and Chalcogen Bonding Interactions in Supramolecular Catalysis

2021 ◽  
Vol 22 (22) ◽  
pp. 12550
Author(s):  
Antonio Frontera ◽  
Antonio Bauza
Keyword(s):  
Electrostatic Potential ◽  
Scientific Community ◽  
Molecular Electrostatic Potential ◽  
Model Systems ◽  
Potential Surfaces ◽  
Supramolecular Catalysis ◽  
Promising Tool ◽  
Group 15 ◽  
Group 16

In this review, several examples of the application of pnictogen (Pn) (group 15) and chalcogen (Ch) bonding (group 16) interactions in organocatalytic processes are gathered, backed up with Molecular Electrostatic Potential surfaces of model systems. Despite the fact that the use of catalysts based on pnictogen and chalcogen bonding interactions is taking its first steps, it should be considered and used by the scientific community as a novel, promising tool in the field of organocatalysis.

Non-renditions and the court interpreter’s perceived impartiality

Interpreting ◽  
2018 ◽  
Vol 20 (2) ◽  
pp. 232-258
Author(s):  
Andrew K. F. Cheung
Keyword(s):  
Experimental Study ◽  
Role Play ◽  
Defense Attorney ◽  
Control Group ◽  
Group 15 ◽  
English Speaking ◽  
Group 16 ◽  
Consecutive Interpreting

Abstract This experimental study examined whether non-renditions are linked to the court interpreter’s perceived impartiality. A witness examination was simulated in three variations on a scripted role play, with consecutive interpreting between Cantonese and English. A sample of female Cantonese speakers, divided into two experimental groups and a control group, each played the part of the witness in one role play; the interpreter and the English-speaking bench (judge and defense attorney) were always played by the same three actors. In two experimental groups, the interpretation included some utterances with no source speech counterpart (non-renditions): a Cantonese non-rendition group (16 individuals) had procedural and textual non-renditions addressed to them in Cantonese, without English interpretation for the bench; an English non-rendition group (15 individuals) heard some brief exchanges between the interpreter and the bench, with no Cantonese interpretation. A control group (15 individuals) was not exposed to non-renditions. All three groups completed a questionnaire after the role play. The English non-rendition group rated the interpreter significantly lower than the others on impartiality, and was also the only group to comment unfavorably on the interpreter. A possible explanation is that the Cantonese speakers in this group could not follow the English non-renditions and felt excluded.

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