Photodissociation ofN-(Triphenylmethyl)anilines:  A Laser Flash Photolysis, ESR, and Product Analysis Study1

1998 ◽  
Vol 63 (10) ◽  
pp. 3251-3259 ◽  
Author(s):  
M. G. Siskos ◽  
A. K. Zarkadis ◽  
S. Steenken ◽  
N. Karakostas ◽  
S. K. Garas
Keyword(s):  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Product Analysis

Hydroxylation of Chlorotoluenes and Cresols: A Pulse Radiolysis, Laser Flash Photolysis, and Product Analysis Study

1997 ◽  
Vol 101 (51) ◽  
pp. 9837-9845 ◽  
Author(s):  
S. C. Choure ◽  
M. M. M. Bamatraf ◽  
B. S. M. Rao ◽  
Ranjan Das ◽  
H. Mohan ◽  
...  
Keyword(s):  
Pulse Radiolysis ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Product Analysis ◽  
Analysis Study

Photodissociation ofN-Arylmethylanilines:  A Laser Flash Photolysis, Fluorescence, and Product Analysis Study1

1999 ◽  
Vol 64 (6) ◽  
pp. 1925-1931 ◽  
Author(s):  
M. G. Siskos ◽  
A. K. Zarkadis ◽  
S. Steenken ◽  
N. Karakostas
Keyword(s):  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Product Analysis

ChemInform Abstract: Photodissociation of N-(Triphenylmethyl)anilines: A Laser Flash Photolysis, ESR, and Product Analysis Study.

ChemInform ◽  
2010 ◽  
Vol 29 (36) ◽  
pp. no-no
Author(s):  
M. G. SISKOS ◽  
A. K. ZARKADIS ◽  
S. STEENKEN ◽  
N. KARAKOSTAS ◽  
S. K. GARAS
Keyword(s):  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Product Analysis ◽  
Analysis Study

Chemistry of photogenerated α-hydroxy-p-nitrobenzyl carbanions in aqueous solution: protonation vs. disproportionation

2003 ◽  
Vol 81 (6) ◽  
pp. 586-597 ◽  
Author(s):  
James Morrison ◽  
Peter Wan ◽  
John ET Corrie ◽  
V Ranjit Munasinghe
Keyword(s):  
Aqueous Solution ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Aldol Reaction ◽  
Laser Flash ◽  
Product Analysis ◽  
Subsequent Reaction ◽  
Reduced Products ◽  
Carbon Acids ◽  
Carbon Acid

The photochemistry of p-nitrobenzyl derivatives 6–10 has been studied in aqueous solution as a function of pH, using product analysis, UV–vis spectrophotometry, and laser flash photolysis (LFP). The compounds were chosen with the aim of further exploring the propensity of these systems to give rise to α-hydroxy-p-nitrobenzyl carbanions on photolysis, and to study their mechanisms of subsequent reaction. α-Hydroxy-substituted carbanions are anions that cannot be readily formed using thermal routes but which are believed to have some interesting chemistry. Three methods were employed for photogenerating these carbanions: (i) decarboxylation; (ii) retro-Aldol reaction; and (iii) carbon acid deprotonation. All three methods proved to be successful using the p-nitrobenzyl chromophore. Photogenerated α-hydroxy-p-nitrobenzyl carbanions react via disproportionation, giving rise to oxidized and reduced products; simple protonation of the anion was undetectable.Key words: photodecarboxylation, nitrobenzyl carbanions, photoredox, nitroaromatic compounds, excited-state carbon acids.

Phototransformation of 5-nitro-2-furaldehyde in aqueous solution. A laser flash photolysis and product analysis study

2017 ◽  
Vol 16 (5) ◽  
pp. 721-735 ◽  
Author(s):  
Luis J. A. Martins ◽  
João M. M. Ferreira
Keyword(s):  
Aqueous Solution ◽  
Triplet State ◽  
Radical Anion ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
The Novel ◽  
Product Analysis ◽  
Analysis Study

The photoreactivity of 5-nitro-2-furaldehyde in solution is ascribed to the lowest triplet state. Evidence that a furyloxyl radical yields 5-hydroxymethyl-2(5H)-furanone, and the radical anion leads to the novel product 5-imino-2(5H)-furanone in water, is presented.

Effect of Aggregation on Bacteriochlorin a Triplet-state Formation: A Laser Flash Photolysis Study¶

2002 ◽  
Vol 76 (5) ◽  
pp. 480 ◽  
Author(s):  
Xavier Damoiseau ◽  
Francis Tfibel ◽  
Maryse Hoebeke ◽  
Marie-Pierre Fontaine-Aupart
Keyword(s):  
Triplet State ◽  
State Formation ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash

A Laser Flash Photolysis and Pulse Radiolysis Study of Primary Photochemical Processes of Flumequine¶

2000 ◽  
Vol 72 (4) ◽  
pp. 451 ◽  
Author(s):  
M. Bazin ◽  
F. Bosca ◽  
M. L. Marin ◽  
M. A. Miranda ◽  
L. K. Patterson ◽  
...  
Keyword(s):  
Pulse Radiolysis ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Photochemical Processes
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