Diethyl Chlorophosphite:  A Mild Reagent for Efficient Reduction of Nitro Compounds to Amines

1998 ◽  
Vol 63 (2) ◽  
pp. 393-395 ◽  
Author(s):  
Bilha Fischer ◽  
Larisa Sheihet
Keyword(s):  
Nitro Compounds ◽  
Efficient Reduction

Green Synthesis of the Ag/Bentonite Nanocomposite Using Euphorbia larica Extract: A Reusable Catalyst for Efficient Reduction of Nitro Compounds and Organic Dyes

2018 ◽  
Vol 3 (43) ◽  
pp. 12274-12280 ◽  
Author(s):  
S. Mohammad Sajadi ◽  
Kamal Kolo ◽  
Samir M. Hamad ◽  
Sarbast. A. Mahmud ◽  
Azeez A. Barzinjy ◽  
...  
Keyword(s):  
Green Synthesis ◽  
Organic Dyes ◽  
Nitro Compounds ◽  
Reusable Catalyst ◽  
Efficient Reduction

Simple and Efficient Reduction of Aromatic Nitro Compounds Using Recyclable Polymer-Supported Formate and Magnesium

2005 ◽  
Vol 58 (2) ◽  
pp. 149 ◽  
Author(s):  
Keelara Abiraj ◽  
Gejjalagere R. Srinivasa ◽  
D. Channe Gowda
Keyword(s):  
Room Temperature ◽  
Low Cost ◽  
Nitro Compounds ◽  
Hydrogen Donor ◽  
Hydroxyl Groups ◽  
Chromatographic Purification ◽  
Aromatic Nitro Compounds ◽  
Efficient Reduction ◽  
Polymer Supported ◽  
Aromatic Nitro

Aromatic nitro compounds were chemoselectively reduced to the corresponding amines using recyclable polymer-supported formate as a hydrogen donor in the presence of low-cost magnesium powder at room temperature. Use of the immobilized hydrogen donor affords the product amine in excellent yield (90–97%) without the need for any chromatographic purification steps. This method was found to be highly facile with selectivity over several other functional groups, such as halogen, alkene, nitrile, carbonyl, ester, amide, methoxy, phenol, and hydroxyl groups.

Efficient reduction of nitroarenes in water catalyzed by reusable Pd nanoparticles immobilized on chitosan-functionalized graphene oxide

2019 ◽  
Vol 97 (3) ◽  
pp. 191-196 ◽  
Author(s):  
Mosayeb Sarvestani ◽  
Roya Azadi
Keyword(s):  
Graphene Oxide ◽  
Pd Nanoparticles ◽  
Nitro Compounds ◽  
Functionalized Graphene ◽  
Efficient Catalyst ◽  
Environmental Friendliness ◽  
Functionalized Graphene Oxide ◽  
Efficient Reduction ◽  
Multiple Cycles ◽  
Aromatic Nitro

Graphene oxide was functionalized with chitosan for palladium immobilization (GO–Chit–Pd), which was used as an efficient catalyst for the reduction of aromatic nitro compounds using sodium borohydride in water. To achieve the best catalytic efficacy, various parameters such as temperature, solvent, mole ratio of hydrogen sources, and the amount of catalyst were optimized. The method has been applied to the reduction of a broad range of nitroarenes with different properties. The easy purification, convenient operation, environmental friendliness, and high product yields render this method viable for use. The nanocatalyst can be easily separated and efficiently recovered and reused for multiple cycles without appreciable loss in its catalytic activity.

scholarly journals Efficient reduction of aromatic nitro compounds catalyzed by nickel chloride supported on natural phosphate

2018 ◽  
Vol 7 (5) ◽  
pp. 317-327 ◽  
Author(s):  
Abderrahim Baba ◽  
Hicham Ouahbi ◽  
Ayoub Hassine ◽  
Jalila Sebti ◽  
Laila Laasri ◽  
...  
Keyword(s):  
Sodium Borohydride ◽  
Room Temperature ◽  
Nickel Chloride ◽  
Nitro Compounds ◽  
Raw Material ◽  
Natural Phosphate ◽  
Aromatic Nitro Compounds ◽  
Efficient Reduction ◽  
Excellent Activity ◽  
Aromatic Nitro

Natural phosphates are an important natural resource in Morocco, which need to be valorized; they can be used not only as primary raw material to produce the fertilizers but also as catalysts. In this work, we have prepared natural phosphate-supported nickel chloride (NiCl2/NP). This material was effectively used as a heterogeneous catalyst in the presence of sodium borohydride as a reducing agent. The reaction was carried out at room temperature in an aqueous medium. The catalyst showed an excellent activity for the reduction of aromatic nitro compounds under simple conditions along with good usability.

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