Practical Synthesis of Enantiopure Cyclic 1,2-Amino Alcohols via Catalytic Asymmetric Ring Opening of Meso Epoxides

1997 ◽  
Vol 62 (12) ◽  
pp. 4197-4199 ◽  
Author(s):  
Scott E. Schaus ◽  
Jay F. Larrow ◽  
Eric N. Jacobsen
Keyword(s):  
Ring Opening ◽  
Amino Alcohols ◽  
Practical Synthesis ◽  
Catalytic Asymmetric ◽  
Asymmetric Ring Opening

Catalytic Asymmetric Transformations of Racemic Aziridines

Synthesis ◽  
2020 ◽  
Vol 52 (12) ◽  
pp. 1738-1750 ◽  
Author(s):  
Zhuo Chai
Keyword(s):  
Ring Opening ◽  
Kinetic Resolution ◽  
Short Review ◽  
Asymmetric Transformations ◽  
Parallel Kinetic Resolution ◽  
Donor Acceptor ◽  
Molecular Architectures ◽  
Catalytic Asymmetric ◽  
Asymmetric Transformation ◽  
Asymmetric Ring Opening

The catalytic asymmetric ring-opening transformations of aziridines represent an important strategy for the construction of various chiral nitrogen-containing molecular architectures. This short review covers the progress achieved in the catalytic asymmetric transformation of racemic aziridines, focusing on the catalytic strategies employed for each different type of such aziridines.1 Introduction2 Reaction of Racemic 2-Vinylaziridines3 Reaction of Racemic 2-Alkylaziridines3.1 Regiodivergent Parallel Kinetic Resolution3.2 Kinetic Resolution4 Reaction of Racemic 2-(Hetero)arylaziridines4.1 Kinetic Resolution4.2 Enantioconvergent Transformation5 Reaction of Racemic Donor–Acceptor-Type Aziridines6 Conclusion and Outlook

Tandem Catalytic Asymmetric Ring-Opening Metathesis/Ring-Closing Metathesis

2000 ◽  
Vol 122 (8) ◽  
pp. 1828-1829 ◽  
Author(s):  
Gabriel S. Weatherhead ◽  
J. Gair Ford ◽  
Erik J. Alexanian ◽  
Richard R. Schrock ◽  
Amir H. Hoveyda
Keyword(s):  
Ring Opening ◽  
Ring Closing Metathesis ◽  
Catalytic Asymmetric ◽  
Asymmetric Ring Opening

Catalytic Asymmetric Ring Opening ofmeso-Epoxides with Aromatic Amines in Water

2005 ◽  
Vol 7 (21) ◽  
pp. 4593-4595 ◽  
Author(s):  
Stéphane Azoulay ◽  
Kei Manabe ◽  
Shū Kobayashi
Keyword(s):  
Aromatic Amines ◽  
Ring Opening ◽  
Catalytic Asymmetric ◽  
Asymmetric Ring Opening

De Novo Synthesis of Tamiflu via a Catalytic Asymmetric Ring-Opening ofmeso-Aziridines with TMSN3

2006 ◽  
Vol 128 (19) ◽  
pp. 6312-6313 ◽  
Author(s):  
Yuhei Fukuta ◽  
Tsuyoshi Mita ◽  
Nobuhisa Fukuda ◽  
Motomu Kanai ◽  
Masakatsu Shibasaki
Keyword(s):  
Ring Opening ◽  
De Novo ◽  
De Novo Synthesis ◽  
Catalytic Asymmetric ◽  
Asymmetric Ring Opening
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