Photosensitized Electron Transfer Promoted Reductive Activation of Carbon−Selenium Bonds To Generate Carbon-Centered Radicals:  Application for Unimolecular Group Transfer Radical Reactions

1996 ◽  
Vol 61 (20) ◽  
pp. 6799-6804 ◽  
Author(s):  
Ganesh Pandey ◽  
K. S. Sesha Poleswara Rao ◽  
K. V. Nageshwar Rao
Keyword(s):  
Electron Transfer ◽  
Radical Reactions ◽  
Reductive Activation ◽  
Group Transfer

scholarly journals Cascades, Catalysis and Chiral Ligand Control with SmI2; The Rebirth of a Reagent

2020 ◽  
Vol 74 (1) ◽  
pp. 18-22
Author(s):  
Áron Péter ◽  
David J. Procter
Keyword(s):  
Electron Transfer ◽  
Cascade Reactions ◽  
Single Electron ◽  
Radical Reactions ◽  
Chiral Ligand ◽  
Single Electron Transfer ◽  
Recent Developments ◽  
Radical Cascade

This review focuses on recent developments from our laboratory in the field of radical reactions mediated by the archetypal reductive single electron transfer (SET) reagent, SmI2. Namely, we have expanded the scope of reducible carbonyl moieties to esters and amides and have exploited the resultant ketyl radicals in radical cascade reactions that generate unprecedented scaffolds. Moreover, we have taken the first steps to address the long-standing challenges of catalysis and chiral ligand control associated with the reagent.

scholarly journals Chiral Nitroarenes as Enantioselective Single-Electron-Transfer Oxidants for Carbene-Catalyzed Radical Reactions

2019 ◽  
Vol 21 (18) ◽  
pp. 7440-7444 ◽  
Author(s):  
Hongling Wang ◽  
Yuhuang Wang ◽  
Xingkuan Chen ◽  
Chengli Mou ◽  
Shuyan Yu ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Single Electron ◽  
Radical Reactions ◽  
Single Electron Transfer

Novel Group-Transfer Radical Reactions with Organotelluriums

Synlett ◽  
2004 ◽  
Vol 2004 (11) ◽  
pp. 1875-1890 ◽  
Author(s):  
Shigeru Yamago
Keyword(s):  
Radical Reactions ◽  
Group Transfer
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