Synthesis of Deuterium-Labeled Plant Sterols and Analysis of Their Side-Chain Mobility by Solid State Deuterium NMR

1996 ◽  
Vol 61 (13) ◽  
pp. 4252-4257 ◽  
Author(s):  
Mary-Pierre Marsan ◽  
William Warnock ◽  
Isabelle Muller ◽  
Yoichi Nakatani ◽  
Guy Ourisson ◽  
...  
Keyword(s):  
Solid State ◽  
Plant Sterols ◽  
Side Chain ◽  
Deuterium Nmr ◽  
Chain Mobility

ChemInform Abstract: Synthesis of Deuterium-Labeled Plant Sterols (I) and (II) and Analysis of Their Side-Chain Mobility by Solid State Deuterium NMR.

ChemInform ◽  
2010 ◽  
Vol 27 (45) ◽  
pp. no-no
Author(s):  
M.-P. MARSAN ◽  
W. WARNOCK ◽  
I. MULLER ◽  
Y. NAKATANI ◽  
G. OURISSON ◽  
...  
Keyword(s):  
Solid State ◽  
Plant Sterols ◽  
Side Chain ◽  
Deuterium Nmr ◽  
Chain Mobility

A Study of Phenylalanine Side-Chain Dynamics in Surface-Adsorbed Peptides Using Solid-State Deuterium NMR and Rotamer Library Statistics

2014 ◽  
Vol 136 (32) ◽  
pp. 11402-11411 ◽  
Author(s):  
Kun Li ◽  
Prashant S. Emani ◽  
Jason Ash ◽  
Michael Groves ◽  
Gary P. Drobny
Keyword(s):  
Solid State ◽  
Side Chain ◽  
Deuterium Nmr ◽  
Chain Dynamics ◽  
Rotamer Library ◽  
Side Chain Dynamics

scholarly journals A Solid-State Deuterium NMR and Sum-Frequency Generation Study of the Side-Chain Dynamics of Peptides Adsorbed onto Surfaces

2009 ◽  
Vol 131 (40) ◽  
pp. 14148-14149 ◽  
Author(s):  
Nicholas F. Breen ◽  
Tobias Weidner ◽  
Kun Li ◽  
David G. Castner ◽  
Gary P. Drobny
Keyword(s):  
Solid State ◽  
Sum Frequency Generation ◽  
Side Chain ◽  
Deuterium Nmr ◽  
Chain Dynamics ◽  
Sum Frequency ◽  
Frequency Generation ◽  
Side Chain Dynamics

Synthesis and solid state structures of macromolecular cylindrical brushes with varying side chain length

Polymer ◽  
2004 ◽  
Vol 45 (12) ◽  
pp. 4009-4015 ◽  
Author(s):  
Bin Zhang ◽  
Shanju Zhang ◽  
Lidia Okrasa ◽  
Tadeusz Pakula ◽  
Tim Stephan ◽  
...  
Keyword(s):  
Solid State ◽  
Chain Length ◽  
Side Chain ◽  
Side Chain Length ◽  
Solid State Structures

Segmental dynamics in the amorphous phase of nylon 66: solid state deuterium NMR

1990 ◽  
Vol 23 (8) ◽  
pp. 2169-2182 ◽  
Author(s):  
H. Miura ◽  
J. Hirschinger ◽  
Alan D. English
Keyword(s):  
Solid State ◽  
Amorphous Phase ◽  
Deuterium Nmr ◽  
Nylon 66 ◽  
Segmental Dynamics

Thermosetting Mechanism Study of Organosilicon Polymer Containing Carborane by Solid-State NMR Spectroscopy

1999 ◽  
Vol 576 ◽  
Author(s):  
H. Kimura ◽  
K. Okita ◽  
M. Ichitani ◽  
M. Yonezawa ◽  
T. Sugimoto
Keyword(s):  
Solid State ◽  
Solid State Nmr ◽  
Nmr Spectra ◽  
Main Chain ◽  
Addition Reaction ◽  
Side Chain ◽  
Mechanism Study ◽  
Nmr Method ◽  
Organosilicon Polymer ◽  
Thermal Stable

ABSTRACTThe thermosetting mechanism of an organosilicon polymer containing carborane has been studied utilizing the 13and 29Si solid-state NMR method. The polymer having C≡C bonds in the main chain and CH═CH2, Si-H bonds, and carborane in the bulky side chain, shows a very highly thermal stability in air by curing. From 13C and 29Si NMR spectra of the polymer, it was found that the intermolecular cross-linking reactions of the polymer was due to (1) the diene reaction between Ph-C≡C and C≡C and (2) the addition reaction between side chain terminal and Ph-C≡C and between CH═CH2 and Si–H, and a very highly thermal stable structure is formed.

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