Nitrogen Inversion Barrier of 2-Methyl-2-azabicyclo[2.2.1]heptane. The Role of Torsional Strain in Pyramidal Inversion

1996 ◽  
Vol 61 (4) ◽  
pp. 1284-1289 ◽  
Author(s):  
David A. Forsyth ◽  
Weiyi Zhang ◽  
John A. Hanley
Keyword(s):  
Inversion Barrier ◽  
Torsional Strain ◽  
Nitrogen Inversion ◽  
Pyramidal Inversion

Nitrogen inversion barrier in cis-N-chloro-2-methylethyleneimine

1969 ◽  
Vol 18 (3) ◽  
pp. 663-663
Author(s):  
R. G. Kostyanovskii ◽  
I. I. Chervin ◽  
V. A. Afanas'ev ◽  
A. A. Fomichev ◽  
Z. E. Samoilova
Keyword(s):  
Inversion Barrier ◽  
Nitrogen Inversion ◽  
In Cis

scholarly journals Functional Role of Extranucleosomal DNA and the Entry Site of the Nucleosome in Chromatin Remodeling by ISW2

2004 ◽  
Vol 24 (22) ◽  
pp. 10047-10057 ◽  
Author(s):  
Martin Zofall ◽  
Jim Persinger ◽  
Blaine Bartholomew
Keyword(s):  
Chromatin Remodeling ◽  
Functional Role ◽  
Minimal Amount ◽  
Dna Fragments ◽  
Entry Site ◽  
Torsional Strain ◽  
Mapping Approach ◽  
Nucleosomal Dna ◽  
Initial Stage

ABSTRACT A minimal amount of extranucleosomal DNA was required for nucleosome mobilization by ISW2 as shown by using a photochemical histone mapping approach to analyze nucleosome movement on a set of nucleosomes with varied lengths of extranucleosomal DNA. ISW2 was ineffective in repositioning or mobilizing nucleosomes with ≤20 bp of extranucleosomal DNA. In addition, ISW2 was able to slide nucleosomes to within only 10 to 13 bp of the edge of DNA fragments. The nucleosome mobilization was promoted by extranucleosomal single-stranded DNA with modest strand preference. Gaps (10 bp) just inside the nucleosome and in the extranucleosomal DNA showed that the transfer of torsional strain (twist) into the nucleosomal DNA region was not required for mobilizing nucleosomes. However, indications are that the extranucleosomal DNA immediately adjacent to the nucleosome has an important role in the initial stage of nucleosome movement by ISW2.

Rate-Determining Role of Strain for Nitrogen Inversion in Polycyclic Tertiary Amines1

1996 ◽  
Vol 118 (33) ◽  
pp. 7783-7789 ◽  
Author(s):  
Anatoly M. Belostotskii ◽  
Hugo E. Gottlieb ◽  
Alfred Hassner
Keyword(s):  
Nitrogen Inversion

Effects of CNN bond angle restriction in 2,3-diazabicyclo[2.1.1]hexane derivatives on nitrogen inversion barrier, ease of oxidation, and acidity

1991 ◽  
Vol 56 (2) ◽  
pp. 613-618 ◽  
Author(s):  
Stephen F. Nelsen ◽  
Peter A. Petillo ◽  
Hao Chang ◽  
Timothy B. Frigo ◽  
Dennis A. Dougherty ◽  
...  
Keyword(s):  
Bond Angle ◽  
Inversion Barrier ◽  
Nitrogen Inversion
Sign in / Sign up

Export Citation Format

Share Document