Lithium and Cesium Ion-Pair Acidities of Some Terminal Acetylenes and Aggregation in Tetrahydrofuran1

1996 ◽  
Vol 61 (5) ◽  
pp. 1742-1747 ◽  
Author(s):  
Roustam Gareyev ◽  
Andrew Streitwieser
Keyword(s):  
Ion Pair ◽  
Cesium Ion ◽  
Terminal Acetylenes

Carbon acidity. 82. Equilibrium cesium ion pair acidities of some substituted 1,3-dithianes

1992 ◽  
Vol 57 (18) ◽  
pp. 4986-4990 ◽  
Author(s):  
Linfeng Xie ◽  
Daniel A. Bors ◽  
Andrew Streitwieser
Keyword(s):  
Ion Pair ◽  
Cesium Ion

First-Principle Calculation of Equilibrium Cesium Ion-Pair Acidities in Tetrahydrofuran

2007 ◽  
Vol 129 (44) ◽  
pp. 13510-13519 ◽  
Author(s):  
Yao Fu ◽  
Kuang Shen ◽  
Lei Liu ◽  
Qing-Xiang Guo
Keyword(s):  
Ion Pair ◽  
First Principle ◽  
Principle Calculation ◽  
First Principle Calculation ◽  
Cesium Ion

Extended lithium ion pair indicator scale in tetrahydrofuran

1998 ◽  
Vol 76 (6) ◽  
pp. 765-769 ◽  
Author(s):  
Andrew Streitwieser ◽  
Daniel Zerong Wang ◽  
Manolis Stratakis ◽  
Antonio Facchetti ◽  
Roustam Gareyev ◽  
...  
Keyword(s):  
Lithium Ion ◽  
Ion Pair ◽  
Organolithium Compounds ◽  
Cesium Ion ◽  
Pk Scale ◽  
Acidity Scale

The lithium pK scale has been extended to 25 indicators with a pK range of 9.7-24.4. The resulting scale is compared with the cesium ion pair acidities and to ionic pK's in DMSO and aqueous DMSO.Key words: ion pair acidity, organolithium compounds, indicator, acidity scale.

Lithium and Cesium Ion-Pair Acidities of Dibenzyl Ketone. Aggregation of Lithium and Cesium Ion Pairs of the Enolate Ion and Dianion1,†

1996 ◽  
Vol 61 (14) ◽  
pp. 4589-4593 ◽  
Author(s):  
Roustam Gareyev ◽  
James C. Ciula ◽  
Andrew Streitwieser
Keyword(s):  
Ion Pairs ◽  
Ion Pair ◽  
Cesium Ion

Carbon acidity. 78. Extended cesium ion pair indicator scale in tetrahydrofuran

1991 ◽  
Vol 56 (3) ◽  
pp. 1074-1076 ◽  
Author(s):  
Andrew Streitwieser ◽  
James C. Ciula ◽  
James A. Krom ◽  
Georg Thiele
Keyword(s):  
Ion Pair ◽  
Cesium Ion

National primary standard of air kerma, air kerma rate, exposure, exposure rate and energy flux for X-rays and gamma radiation GET 8-2019

2020 ◽  
pp. 8-12
Author(s):  
Alexandr V. Oborin ◽  
Anna Y. Villevalde ◽  
Sergey G. Trofimchuk
Keyword(s):  
Gamma Radiation ◽  
Energy Flux ◽  
Primary Standard ◽  
Average Energy ◽  
Ion Pair ◽  
X Rays ◽  
Exposure Rate ◽  
Ionization Chambers ◽  
Air Kerma ◽  
Air Kerma Rate

The results of development of the national primary standard of air kerma, air kerma rate, exposure, exposure rate and energy flux for X-rays and gamma radiation GET 8-2011 in 2019 are presented according to the recommendations of the ICRU Report No. 90 “Key Data for Ionizing-Radiation Dosimetry: Measurement Standards and Applications”. The following changes are made to the equations for the units determination with the standard: in the field of X-rays, new correction coefficients of the free-air ionization chambers are introduced and the relative standard uncertainty of the average energy to create an ion pair in air is changed; in the field of gamma radiation, the product of the average energy to create an ion pair in air and the electron stopping-power graphite to air ratio for the cavity ionization chambers is changed. More accurate values of the units reproduced by GET 8-2019 are obtained and new metrological characteristics of the standard are stated.

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