scholarly journals A Synthetic Approach to Ervatamine-Silicine Alkaloids. Enantioselective Total Synthesis of (−)-16-Episilicine†

2010 ◽  
Vol 75 (1) ◽  
pp. 178-189 ◽  
Author(s):  
Mercedes Amat ◽  
Núria Llor ◽  
Begoña Checa ◽  
Elies Molins ◽  
Joan Bosch
Keyword(s):  
Total Synthesis ◽  
Synthetic Approach ◽  
Enantioselective Total Synthesis

Enantioselective total synthesis of (+)-serinolamide A

RSC Advances ◽  
2015 ◽  
Vol 5 (51) ◽  
pp. 41013-41016 ◽  
Author(s):  
Suraksha Gahalawat ◽  
Satyendra Kumar Pandey
Keyword(s):  
Total Synthesis ◽  
Starting Material ◽  
Synthetic Approach ◽  
Enantioselective Total Synthesis ◽  
Highly Efficient

A short and highly efficient enantioselective synthetic approach to (+)-serinolamide A 1 from racemic butadiene monoepoxide as a starting material is described.

Enantioselective total synthesis of colomitides and their absolute configuration determination and structural revision

2017 ◽  
Vol 15 (17) ◽  
pp. 3728-3735 ◽  
Author(s):  
Hongguang Yang ◽  
Xiaoyu Liu ◽  
Xiaoyu Li ◽  
Xiang Shi ◽  
Feilong Yang ◽  
...  
Keyword(s):  
Natural Products ◽  
Total Synthesis ◽  
Absolute Configuration ◽  
Synthetic Approach ◽  
Enantioselective Total Synthesis ◽  
Structural Revision

An efficient stereoselective synthetic approach to colomitides, 2,7-dioxabicyclo[3.2.1]octane-type natural products, is reported.

General Cyclopropane Assembly via Enantioselective Redox-Active Carbene Transfer to Aliphatic Olefins

2018 ◽  
Author(s):  
Marc Montesinos-Magraner ◽  
Matteo Costantini ◽  
Rodrigo Ramirez-Contreras ◽  
Michael E. Muratore ◽  
Magnus J. Johansson ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Asymmetric Synthesis ◽  
Chemical Space ◽  
Synthetic Approach ◽  
Asymmetric Cyclopropanation ◽  
Redox Active ◽  
Wide Range ◽  
Leaving Group ◽  
Stereoelectronic Properties ◽  
Carbene Transfer

Asymmetric cyclopropane synthesis currently requires bespoke strategies, methods, substrates and reagents, even when targeting similar compounds. This limits the speed and chemical space available for discovery campaigns. Here we introduce a practical and versatile diazocompound, and we demonstrate its performance in the first unified asymmetric synthesis of functionalized cyclopropanes. We found that the redox-active leaving group in this reagent enhances the reactivity and selectivity of geminal carbene transfer. This effect enabled the asymmetric cyclopropanation of a wide range of olefins including unactivated aliphatic alkenes, enabling the 3-step total synthesis of (–)-dictyopterene A. This unified synthetic approach delivers high enantioselectivities that are independent of the stereoelectronic properties of the functional groups transferred. Our results demonstrate that orthogonally-differentiated diazocompounds are viable and advantageous equivalents of single-carbon chirons<i>.</i>

scholarly journals Enantioselective Total Synthesis of (+)‐Garsubellin A

2021 ◽  
Author(s):  
Dongseok Jang ◽  
Minchul Choi ◽  
Jinglong Chen ◽  
Chulbom Lee
Keyword(s):  
Total Synthesis ◽  
Enantioselective Total Synthesis

Enantioselective Total Synthesis of ( – )‐Spiroxins A, C and D

2021 ◽  
Author(s):  
Xin Shu ◽  
Chong-Chong Chen ◽  
Tao Yu ◽  
Jiayi Yang ◽  
Xiangdong Hu
Keyword(s):  
Total Synthesis ◽  
Enantioselective Total Synthesis

Unified enantioselective total synthesis of 3,6-dioxygenated diketopiperazine natural products, diatretol and lepistamides A, B and C

2021 ◽  
Vol 67 ◽  
pp. 152895
Author(s):  
Shu Takahashi ◽  
Aoi Kimishima ◽  
Tomoyasu Hirose ◽  
Takeshi Yamada ◽  
Akihiro Sugawara ◽  
...  
Keyword(s):  
Natural Products ◽  
Total Synthesis ◽  
Enantioselective Total Synthesis

Enantioselective total synthesis of sesquiterpenoid phellilane L and its diastereomer

Tetrahedron ◽  
2021 ◽  
Vol 87 ◽  
pp. 132110
Author(s):  
Gullapalli Kumaraswamy ◽  
Vankudoth Ramesh ◽  
Swargam Vijaykumar
Keyword(s):  
Total Synthesis ◽  
Enantioselective Total Synthesis

A concise enantioselective total synthesis of rhizoxin D

2002 ◽  
Vol 43 (3) ◽  
pp. 493-497 ◽  
Author(s):  
Ian S. Mitchell ◽  
Gerald Pattenden ◽  
Jeffrey P. Stonehouse
Keyword(s):  
Total Synthesis ◽  
Enantioselective Total Synthesis ◽  
Rhizoxin D

ChemInform Abstract: An Enantioselective Total Synthesis of (+)-Cassiol.

ChemInform ◽  
2010 ◽  
Vol 28 (15) ◽  
pp. no-no
Author(s):  
O. IRIE ◽  
Y. FUJIWARA ◽  
H. NEMOTO ◽  
K. SHISHIDO
Keyword(s):  
Total Synthesis ◽  
Enantioselective Total Synthesis
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