Effect of Aromatic−Aromatic Interactions on the Conformational Stabilities of Macrocycle and Preorganized Structure during Macrocyclization

2009 ◽  
Vol 74 (7) ◽  
pp. 2804-2810 ◽  
Author(s):  
Kosuke Katagiri ◽  
Taichi Tohaya ◽  
Hyuma Masu ◽  
Masahide Tominaga ◽  
Isao Azumaya
Keyword(s):  
Aromatic Interactions

Controlling enantioselectivity of esterase in asymmetric hydrolysis of aryl prochiral diesters by introducing aromatic interactions

2014 ◽  
Vol 111 (9) ◽  
pp. 1729-1739 ◽  
Author(s):  
Fei Guo ◽  
Stefan Franzen ◽  
Lidan Ye ◽  
Jiali Gu ◽  
Hongwei Yu
Keyword(s):  
Aromatic Interactions ◽  
Hydrolysis Of

Carbohydrate-Aromatic Interactions: The Role of Curvature on XH···π Interactions

2010 ◽  
Vol 114 (12) ◽  
pp. 4313-4324 ◽  
Author(s):  
R. Mahesh Kumar ◽  
M. Elango ◽  
V. Subramanian
Keyword(s):  
Π Interactions ◽  
Aromatic Interactions

Aromatic interactions in Glycochemistry: from molecular recognition to catalysis

2021 ◽  
Vol 28 ◽  
Author(s):  
Andrés González Santana ◽  
Laura Díaz-Casado ◽  
Laura Montalvillo ◽  
Ester Jiménez-Moreno ◽  
Enrique Mann ◽  
...  
Keyword(s):  
Molecular Recognition ◽  
Transition States ◽  
Carbohydrate Binding ◽  
Potential Influence ◽  
Chemical Structures ◽  
Receptor Complexes ◽  
Binding Domains ◽  
Aromatic Interactions ◽  
Aromatic Complexes ◽  
Recognition Motifs

: Aromatic platforms are ubiquitous recognition motifs occurring in protein carbohydrate binding domains (CBDs), RNA receptors and enzymes. They stabilize the glycoside/receptor complexes by participating in stacking CH/ interactions with either the - or - face of the corresponding pyranose units. In addition, the role played by aromatic units in the stabilization of glycoside cationic transition states has started being recognized in recent years. Extensive studies carried out during the last decade have allowed to dissect the main contributing forces that stabilize the carbohydrate/aromatic complexes, while helping delineate not only the standing relationship between the glycoside/aromatic chemical structures and the strength of this interaction, but also their potential influence on glycoside reactivity.

Twisting and piezochromism of phenylene-ethynylenes with aromatic interactions between side chains and main chains

2014 ◽  
Vol 5 (11) ◽  
pp. 4184-4188 ◽  
Author(s):  
R. H. Pawle ◽  
T. E. Haas ◽  
P. Müller ◽  
S. W. Thomas III
Keyword(s):  
Solid State ◽  
Side Chains ◽  
Aromatic Interactions ◽  
Phenylene Ethynylenes

This paper describes a series of three-ring phenylene-ethynylenes (PEs) in which specific, non-covalent arene–arene interactions control conformation in the solid-state.

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