Polyfunctional Tetrazolic Thioethers through Electrooxidative/Michael-Type Sequential Reactions of 1,2- and 1,4-Dihydroxybenzenes with 1-Phenyl-5-mercaptotetrazole

2008 ◽  
Vol 73 (7) ◽  
pp. 2527-2532 ◽  
Author(s):  
Mohammad M. Khodaei ◽  
Abdolhamid Alizadeh ◽  
Narges Pakravan
Keyword(s):  
2018 ◽  
Author(s):  
Richard Kong ◽  
Mark Crimmin

<i>The formation of carbon chains by the coupling of COx (X = 1 or 2) units on transition metals is a fundamental step relevant to Fischer-Tropsch catalysis. Fischer-Tropsch catalysis produces energy dense liquid hydrocarbons from synthesis gas (CO and H2) and has been a mainstay of the energy economy since its discovery nearly a century ago. Despite detailed studies aimed at elucidating the steps of catalysis, experimental evidence for chain growth (Cn to Cn+1 ; n > 2) from the reaction of CO with metal complexes is unprecedented. In this paper, we show that carbon chains can be grown from sequential reactions of CO or CO2 with a transition metal carbonyl complex. By exploiting the cooperative effect of transition and main group metals, we document the first example of chain propagation from sequential coupling of CO units (C1 to C3 to C4), along with the first example of incorporation of CO2 into the growing carbon chain.</i><br>


1989 ◽  
Vol 28 (12) ◽  
pp. 1743-1748 ◽  
Author(s):  
Ming Chow ◽  
Gary B. McVicker
Keyword(s):  

Synlett ◽  
2015 ◽  
Vol 26 (08) ◽  
pp. 1031-1038 ◽  
Author(s):  
Aziz Shahrisa ◽  
Reza Teimuri-Mofrad ◽  
Mahdi Gholamhosseini-Nazari

Novel sequential Betti–Ullmann and Betti–C–H activation reactions for the synthesis of 12H-benzo[a]xanthenes and dihydro-1H-naphtho[1,2-e][1,3]oxazines have been developed. Depending on the used conditions selective Ullmann-type arylation or α-C-H aryloxylation of 2-bromophenyl alkylaminonaphthols occurred. A simple, fast, green, and high-yielding method for the synthesis of aminonaphthols catalyzed by bismuth(III) chloride under solvent-free conditions is reported.


2012 ◽  
Vol 53 (44) ◽  
pp. 5916-5919 ◽  
Author(s):  
Tomoya Hirano ◽  
Haruko Kubo ◽  
Takuya Shiraishi ◽  
Kenichi Hiromoto ◽  
Takashi Fujiwara ◽  
...  

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