5-Exoversus 6-EndoCyclization of Primary Aminyl Radicals:  An Experimental and Theoretical Investigation

2007 ◽  
Vol 72 (26) ◽  
pp. 10231-10234 ◽  
Author(s):  
Feng Liu ◽  
Kun Liu ◽  
Xinting Yuan ◽  
Chaozhong Li
Keyword(s):  
Theoretical Investigation ◽  
Aminyl Radicals

Theoretical investigation of a possible new class of stable aminyl radicals

1988 ◽  
Vol 53 (9) ◽  
pp. 2128-2139 ◽  
Author(s):  
Georges Leroy ◽  
Michel Sana ◽  
Claude Wilante
Keyword(s):  
Theoretical Investigation ◽  
Electron Donor ◽  
Stabilization Energy ◽  
General Definition ◽  
Original Result ◽  
New Class ◽  
Aminyl Radicals ◽  
Thermodynamic Stabilization ◽  
Definition Of

We show in this paper that nitrogen-centred radicals carrying two electron-donor substituents constitute a possible new class of stable aminyl radicals. An interpretation of this original result is given by using a general definition of the thermodynamic stabilization energy.

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