Stereoconvergent [1,2]- and [1,4]-Wittig Rearrangements of 2-Silyl-6-aryl-5,6-dihydropyrans: A Tale of Steric vs Electronic Regiocontrol of Divergent Pathways

Luis M. Mori-Quiroz; Robert E. Maleczka

doi:10.1021/jo5026942

Stereoconvergent [1,2]- and [1,4]-Wittig Rearrangements of 2-Silyl-6-aryl-5,6-dihydropyrans: A Tale of Steric vs Electronic Regiocontrol of Divergent Pathways

The Journal of Organic Chemistry ◽

10.1021/jo5026942 ◽

2015 ◽

Vol 80 (2) ◽

pp. 1163-1191 ◽

Cited By ~ 16

Author(s):

Luis M. Mori-Quiroz ◽

Robert E. Maleczka

Keyword(s):

Wittig Rearrangements

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Wittig Rearrangements of (Heteroaryl)alkyl Propargyl Ethers — Synthesis of Allenic and Propargylic Alcohols.

ChemInform ◽

10.1002/chin.200306045 ◽

2003 ◽

Vol 34 (6) ◽

Author(s):

Saverio Florio ◽

Catia Granito ◽

Giovanni Ingrosso ◽

Luigino Troisi

Keyword(s):

Propargylic Alcohols ◽

Wittig Rearrangements

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ChemInform Abstract: VINYL MIGRATION IN WITTIG REARRANGEMENTS

Chemischer Informationsdienst ◽

10.1002/chin.197426184 ◽

1974 ◽

Vol 5 (26) ◽

pp. no-no

Author(s):

VALENTIN RAUTENSTRAUCH ◽

GEORGE BUECHI ◽

HANS WUEEST

Keyword(s):

Wittig Rearrangements

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[1,4]-Wittig Rearrangements

Category 5, Compounds with One Saturated Carbon Heteroatom Bond ◽

10.1055/sos-sd-036-00829 ◽

2008 ◽

pp. 1

Author(s):

J. V. Morey ◽

A. E. H. Wheatley

Keyword(s):

Wittig Rearrangements

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[2,3]-Wittig Rearrangements

Category 5, Compounds with One Saturated Carbon Heteroatom Bond ◽

10.1055/sos-sd-036-00828 ◽

2008 ◽

pp. 1

Author(s):

J. V. Morey ◽

A. E. H. Wheatley

Keyword(s):

Wittig Rearrangements

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ChemInform Abstract: Switching of the Reaction Pathway for (1,2)/(1,4)- and (2,3)-Wittig Rearrangements of 3-Aryl-2-propenyl Propargyl Ethers.

ChemInform ◽

10.1002/chin.198903082 ◽

1989 ◽

Vol 20 (3) ◽

Author(s):

K. HAYAKAWA ◽

A. HAYASHIDA ◽

K. KANEMATSU

Keyword(s):

Reaction Pathway ◽

Wittig Rearrangements

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Application of [2,3] sigmatropic (Wittig) rearrangements in synthesis. The synthesis of (+)-Prelog-Djerassi lactone

Journal of the American Chemical Society ◽

10.1021/ja00299a026 ◽

1985 ◽

Vol 107 (13) ◽

pp. 3915-3918 ◽

Cited By ~ 31

Author(s):

David J. S. Tsai ◽

M. Mark Midland

Keyword(s):

Wittig Rearrangements

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[2,3]-Thia-Wittig Rearrangements of α-Lithiated Sulfides Via De-aromatized Cyclohexadiene Intermediates Proceed with Inversion of Configuration at the Carbanionic Center

Chemische Berichte ◽

10.1002/cber.19941271019 ◽

1994 ◽

Vol 127 (10) ◽

pp. 1949-1957 ◽

Cited By ~ 13

Author(s):

Kay Brickmann ◽

Frank Hambloch ◽

Emanuela Spolaore ◽

Reinhard Brückner

Keyword(s):

Wittig Rearrangements

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ChemInform Abstract: APPLICATION OF (2,3) SIGMATROPIC (WITTIG) REARRANGEMENTS IN SYNTHESIS. THE SYNTHESIS OF (+)-PRELOG-DJERASSI LACTONE

Chemischer Informationsdienst ◽

10.1002/chin.198542361 ◽

1985 ◽

Vol 16 (42) ◽

Author(s):

D. J.-S. TSAI ◽

M. M. MIDLAND

Keyword(s):

Wittig Rearrangements

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Stereoselective Synthesis of Highly FunctionalizedC-Glycosides based on Acetal [1,2] and [1,4] Wittig Rearrangements

Angewandte Chemie International Edition ◽

10.1002/1521-3773(20001215)39:24<4500::aid-anie4500>3.0.co;2-w ◽

2000 ◽

Vol 39 (24) ◽

pp. 4500-4502 ◽

Cited By ~ 27

Author(s):

Katsuhiko Tomooka ◽

Hiroshi Yamamoto ◽

Takeshi Nakai

Keyword(s):

Stereoselective Synthesis ◽

Wittig Rearrangements

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ChemInform Abstract: Different Transition Structures for (2,3)-Wittig Rearrangements of Stabilized and Unstabilized Allyloxy Methyl Anions: Rationale for the Dichotomous Sense of Stereoselection.

ChemInform ◽

10.1002/chin.199439074 ◽

2010 ◽

Vol 25 (39) ◽

pp. no-no

Author(s):

K. MIKAMI ◽

T. UCHIDA ◽

T. HIRANO ◽

Y. WU ◽

K. N. HOUK

Keyword(s):

Wittig Rearrangements ◽

Transition Structures

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