Iron(III) Sulfate as Terminal Oxidant in the Synthesis of Methyl Ketones via Wacker Oxidation

2014 ◽  
Vol 79 (12) ◽  
pp. 5787-5793 ◽  
Author(s):  
Rodney A. Fernandes ◽  
Dipali A. Chaudhari
Keyword(s):  
Methyl Ketones ◽  
Wacker Oxidation

Eliminative Wacker Oxidation: An Efficient Synthesis of α-Alkyl Vinyl Methyl Ketones

Synthesis ◽  
2005 ◽  
Vol 2005 (17) ◽  
pp. 2939-2945 ◽  
Author(s):  
Mukund G. Kulkarni ◽  
Saryu I. Davawala ◽  
Aniruddha K. Doke ◽  
Dnyaneshwar D. Gaikwad ◽  
Ajit V. Doke
Keyword(s):  
Methyl Ketones ◽  
Efficient Synthesis ◽  
Vinyl Methyl ◽  
Wacker Oxidation

Eliminative Wacker Oxidation: An Efficient Synthesis of α-Alkyl Vinyl Methyl Ketones.

ChemInform ◽  
2006 ◽  
Vol 37 (13) ◽  
Author(s):  
Mukund G. Kulkarni ◽  
Saryu I. Davawala ◽  
Aniruddha K. Doke ◽  
Dnyaneswar D. Gaikwad ◽  
Ajit V. Doke
Keyword(s):  
Methyl Ketones ◽  
Efficient Synthesis ◽  
Vinyl Methyl ◽  
Wacker Oxidation

MnO2 as a terminal oxidant in Wacker oxidation of homoallyl alcohols and terminal olefins

2020 ◽  
Vol 18 (31) ◽  
pp. 6115-6125 ◽  
Author(s):  
Rodney A. Fernandes ◽  
Gujjula V. Ramakrishna ◽  
Venkati Bethi
Keyword(s):  
Methyl Ketones ◽  
Reaction Conditions ◽  
Wacker Oxidation ◽  
Terminal Olefins

Efficient and mild reaction conditions for Wacker-type oxidation of terminal olefins of less explored homoallyl alcohols to β-hydroxy-methyl ketones have been developed by using a Pd(ii) catalyst and MnO2 as a co-oxidant.

Acetyl Nitrate Mediated Conversion of Methyl Ketones to Diverse Carboxylic Acid Derivatives

2021 ◽  
Author(s):  
Joseph N. Capilato ◽  
Peter J Pellegrinelli ◽  
Josephine Bernard ◽  
Logan Schnorbus ◽  
Shane Philippi ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Methyl Ketones ◽  
Oxidative Conversion ◽  
Haloform Reaction ◽  
Acetyl Nitrate

The development of a novel acetyl nitrate mediated oxidative conversion of methyl ketones to carboxylic acid derivatives is described. By analogy to the haloform reaction and supported by experimental and...

scholarly journals Manganese vacancy-confined single-atom Ag in cryptomelane nanorods for efficient Wacker oxidation of styrene derivatives

2021 ◽  
Author(s):  
Hongling Yang ◽  
Xun Zhang ◽  
Yi Yu ◽  
Zheng Chen ◽  
Qinggang Liu ◽  
...  
Keyword(s):  
Molecular Sieve ◽  
Active Sites ◽  
Single Atom ◽  
Wacker Oxidation ◽  
Catalytically Active ◽  
Styrene Derivatives

Single-atom catalysts provide a pathway to elucidate the nature of catalytically active sites. However, keeping them stabilized during operation proves to be challenging. Herein, we employ cryptomelane-type octahedral molecular sieve...

Facile Approach to Geminal Heterodihalogenation. One-Pot Synthesis of α-Bromo-α-Chloro Ketones

Synlett ◽  
2020 ◽  
Vol 31 (14) ◽  
pp. 1430-1434
Author(s):  
Ming Bian ◽  
Jin-feng Zhou ◽  
Dong-min Tang
Keyword(s):  
Drug Discovery ◽  
Dimethyl Sulfoxide ◽  
Functional Groups ◽  
Methyl Ketones ◽  
One Pot ◽  
One Pot Synthesis ◽  
Operational Simplicity

An efficient and practical protocol for the geminal heterodihalogenation of methyl ketones by using readily available dimethyl sulfoxide and a combination of HCl and HBr is reported. Control experiments suggested that the acidity of the solution, as well as the oxidizing ability and nucleophilicity of the dimethyl sulfoxide might work cooperatively in ensuring the success of the tandem substitution. Its operational simplicity, easy accessibility, and mild oxidative conditions suggest that the present strategy might be useful for the assembly of bromochloromethyl functional groups in drug discovery.

scholarly journals Innentitelbild: Chemoselective Oxidative C(CO)C(methyl) Bond Cleavage of Methyl Ketones to Aldehydes Catalyzed by CuI with Molecular Oxygen (Angew. Chem. 43/2013)

2013 ◽  
Vol 125 (43) ◽  
pp. 11384-11384
Author(s):  
Lin Zhang ◽  
Xihe Bi ◽  
Xiaoxue Guan ◽  
Xingqi Li ◽  
Qun Liu ◽  
...  
Keyword(s):  
Molecular Oxygen ◽  
Bond Cleavage ◽  
Methyl Ketones
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