Oxidative Dimerization of (Hetero)aromatic Amines Utilizing t-BuOI Leading to (Hetero)aromatic Azo Compounds: Scope and Mechanistic Studies

2013 ◽  
Vol 78 (23) ◽  
pp. 12090-12105 ◽  
Author(s):  
Sota Okumura ◽  
Chun-Hsuan Lin ◽  
Youhei Takeda ◽  
Satoshi Minakata
Keyword(s):  
Aromatic Amines ◽  
Azo Compounds ◽  
Mechanistic Studies ◽  
Oxidative Dimerization ◽  
Aromatic Azo Compounds

Oxidative Dimerization of Aromatic Amines usingtBuOI: Entry to Unsymmetric Aromatic Azo Compounds

2012 ◽  
Vol 124 (31) ◽  
pp. 7924-7928 ◽  
Author(s):  
Youhei Takeda ◽  
Sota Okumura ◽  
Satoshi Minakata
Keyword(s):  
Aromatic Amines ◽  
Azo Compounds ◽  
Oxidative Dimerization ◽  
Aromatic Azo Compounds

Bifunctional Au/Co3O4‐Cs (Basic and Redox)‐ Catalyzed Oxidative Synthesis of Aromatic Azo Compounds from Anilines

2021 ◽  
Author(s):  
Charles O. Oseghale ◽  
Dele Peter Fapojuwo ◽  
Oyekunle Azeez Alimi ◽  
Christianah Aarinola Akinnawo ◽  
Batsile M. Mogudi ◽  
...  
Keyword(s):  
Azo Compounds ◽  
Aromatic Azo Compounds

Gold-Catalyzed Synthesis of Aromatic Azo Compounds from Anilines and Nitroaromatics

Science ◽  
2008 ◽  
Vol 322 (5908) ◽  
pp. 1661-1664 ◽  
Author(s):  
A. Grirrane ◽  
A. Corma ◽  
H. Garcia
Keyword(s):  
Azo Compounds ◽  
Aromatic Azo Compounds

ChemInform Abstract: THE REDUCTIVE HALOGENATION OF AROMATIC AZO COMPOUNDS

1975 ◽  
Vol 6 (51) ◽  
pp. no-no
Author(s):  
BRYCE D. WILKINSON ◽  
DUNCAN A. R. HAPPER
Keyword(s):  
Azo Compounds ◽  
Aromatic Azo Compounds

Massenspektrometrische Untersuchungen an Borchelaten, V [1] Fragmentierung borhaltiger aromatischer Azoverbindungen / Mass Spectrometric Investigation of Boron Chelates, V [1]Fragmentation of Aromatic Azo Compounds Containing Boron

1980 ◽  
Vol 35 (3) ◽  
pp. 316-318 ◽  
Author(s):  
Eberhard Hohaus ◽  
Wolfgang Riepe ◽  
Klaus Wessendorf
Keyword(s):  
Chelate Ring ◽  
Mass Spectrometric ◽  
Azo Compounds ◽  
Spectrometric Investigation ◽  
Mass Spectrometric Investigation ◽  
Boron Chelates ◽  
Molecular Ion ◽  
Significant Change ◽  
Structural Formulae ◽  
Aromatic Azo Compounds

Differing fragmentation of boron chelates of aromatic azo compounds confirms the structural formulae 1a-7c, presented in [2].More significant differences are caused by the substituent of the boron R (F instead of C6H5).Although certain rules can be deduced by the substitution of F for CeHs with regard to the change in intensity of the ions M+, M+-R (and others), in some cases the stable aromatic azo system causes a significant change in the fragmentation as compared with that of azomethine chelates. The chelates 7 eliminate “RH” and show no molecular ion. Apparently a second chelate ring is closed before further fragmentation can start. Fragmentation of 7 a and b is analogous to 5.

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