scholarly journals “Nok”: A Phytosterol-Based Amphiphile Enabling Transition-Metal-Catalyzed Couplings in Water at Room Temperature

2014 ◽  
Vol 79 (3) ◽  
pp. 888-900 ◽  
Author(s):  
Piyatida Klumphu ◽  
Bruce H. Lipshutz
Keyword(s):  
Transition Metal ◽  
Room Temperature ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Ruthenium-Catalyzed Room-Temperature Coupling of α-Keto Sulfoxonium Ylides and Cyclopropanols for δ-Diketone Synthesis

2021 ◽  
Author(s):  
Lili Fang ◽  
Shuaixin Fan ◽  
Tielei Li ◽  
Weiping Wu ◽  
Jin Zhu
Keyword(s):  
Transition Metal ◽  
Room Temperature ◽  
Low Cost ◽  
Rhodium Catalyst ◽  
Catalytic Method ◽  
Reaction Conditions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Previous transition metal-catalyzed synthesis of δ-diketones is plagued by high cost of rhodium catalyst and harsh reaction conditions. Herein a low-cost, room temperature ruthenium catalytic method is developed based on...

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