Oxone-Mediated Oxidative Cleavage of β-Keto Esters and 1,3-Diketones to α-Keto Esters and 1,2-Diketones in Aqueous Medium

2013 ◽  
Vol 78 (14) ◽  
pp. 7268-7273 ◽  
Author(s):  
Anastasios Stergiou ◽  
Anna Bariotaki ◽  
Dimitris Kalaitzakis ◽  
Ioulia Smonou
Keyword(s):  
Aqueous Medium ◽  
Oxidative Cleavage ◽  
Keto Esters

scholarly journals Retraction of “Oxone-Mediated Oxidative Cleavage of β-Keto Esters and 1,3-Diketones to α-Keto Esters and 1,2-Diketones in Aqueous Medium”

2020 ◽  
Vol 85 (2) ◽  
pp. 1324-1324 ◽  
Author(s):  
Anastasios Stergiou ◽  
Anna Bariotaki ◽  
Dimitris Kalaitzakis ◽  
Ioulia Smonou
Keyword(s):  
Aqueous Medium ◽  
Oxidative Cleavage ◽  
Keto Esters

ChemInform Abstract: Oxone-Mediated Oxidative Cleavage of β-Keto Esters and 1,3-Diketones to α-Keto Esters and 1,2-Diketones in Aqueous Medium.

ChemInform ◽  
2013 ◽  
Vol 44 (49) ◽  
pp. no-no
Author(s):  
Anastasios Stergiou ◽  
Anna Bariotaki ◽  
Dimitris Kalaitzakis ◽  
Ioulia Smonou
Keyword(s):  
Aqueous Medium ◽  
Oxidative Cleavage ◽  
Keto Esters

Synthesis of α-Keto Esters and Amides via Oxidative Cleavage of Cyanoketophosphoranes by Dimethyldioxirane

2001 ◽  
Vol 66 (10) ◽  
pp. 3606-3609 ◽  
Author(s):  
Man-Kin Wong ◽  
Chun-Wing Yu ◽  
Wai-Hung Yuen ◽  
Dan Yang
Keyword(s):  
Oxidative Cleavage ◽  
Keto Esters

Copper-catalyzed TEMPO oxidative cleavage of 1,3-diketones and β-keto esters for the synthesis of 1,2-diketones and α-keto esters

2017 ◽  
Vol 15 (12) ◽  
pp. 2629-2637 ◽  
Author(s):  
Peng-Jun Zhou ◽  
Cheng-Kun Li ◽  
Shao-Fang Zhou ◽  
Adedamola Shoberu ◽  
Jian-Ping Zou
Keyword(s):  
Oxidative Cleavage ◽  
Keto Esters

Copper-catalyzed, TEMPO oxidized cleavage of α-methylene of 1,3-diketones and β-keto esters to form 1,2-diketones and α-keto esters.

One-Pot Telescoped Synthesis of Thiazole Derivatives from β-Keto Esters and Thioureas Promoted by Tribromoisocyanuric Acid

Synthesis ◽  
2018 ◽  
Vol 50 (24) ◽  
pp. 4867-4874 ◽  
Author(s):  
Marcio de Mattos ◽  
Vitor de Andrade
Keyword(s):  
Aqueous Medium ◽  
Thiazole Derivatives ◽  
One Pot ◽  
Keto Esters ◽  
Single Process

A simple and efficient one-pot protocol has been developed for the synthesis of thiazole derivatives from readily available starting materials. Tribromoisocyanuric acid was successfully used for α-monohalogenation of β-keto esters in aqueous medium, which in the presence of thiourea and DABCO produced the corresponding 2-aminothiazoles in up to 87% yield. Extension of the reaction to thioacetamide and o-phenylenediamine led to 2-methylthiazole and quinoxalines, respectively. This approach enables telescoping of the two steps into a single process.

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