Trialkyl Phosphites and Diaryliodonium Salts as Co-initiators in a System for Radical-Promoted Visible-Light-Induced Cationic Polymerization

2013 ◽  
Vol 78 (8) ◽  
pp. 3561-3569 ◽  
Author(s):  
Thomas W. Nalli ◽  
Lee G. Stanek ◽  
Rebekka H. Molenaar ◽  
Krysia L. Weidell ◽  
Justin P. Meyer ◽  
...  
Keyword(s):  
Visible Light ◽  
Cationic Polymerization ◽  
Diaryliodonium Salts ◽  
Trialkyl Phosphites

A Visible Light Initiating System for Free Radical Promoted Cationic Polymerization

1994 ◽  
Vol 27 (14) ◽  
pp. 3683-3693 ◽  
Author(s):  
Yubai Bi ◽  
Douglas C. Neckers
Keyword(s):  
Free Radical ◽  
Visible Light ◽  
Cationic Polymerization

scholarly journals Visible Light-Controlled Living Cationic Polymerization of Methoxystyrene

2021 ◽  
Author(s):  
Lei Wang ◽  
Shaodong Zhang ◽  
Yongfeng Zhou ◽  
Yupo Xu ◽  
Quan Zuo ◽  
...  
Keyword(s):  
Visible Light ◽  
Cationic Polymerization ◽  
Molar Mass ◽  
Chain Transfer ◽  
Polymerization Reaction ◽  
Great Success ◽  
Living Cationic Polymerization ◽  
Green Led ◽  
Polymerization System ◽  
Lytic System

Photo-controlled living polymerization has received great attention in recent years. However, despite the great success therein, the report on photo-controlled living cationic polymerization has been greatly limited. We demonstrate here a novel decolorable, metal-free and visible light-controlled living cationic polymerization system by using tris(2,4-dimethoxyphenyl)methylium tetrafluoroborate as the photocatalyst and phosphate as the chain transfer agent (CTA) for polymerization of 4-methoxystyrene. This polymerization reaction under green LED light irradiation shows clear living characteristics including predictable molar mass, narrow molar-mass dispersity (Đ = 1.25), and sequential polymerization capability. In addition, the photocata-lytic system exits excellent “on-off” photo switchability and shows the longest “off period” of 36 h up to now for photo-controlled cationic polymerization. Furthermore, the residual photo-catalyst is easily deactivated and decolored with addition of a base after the polymerization.

Visible Light-Induced Cationic Polymerization Using Fullerenes

2012 ◽  
Vol 1 (10) ◽  
pp. 1212-1215 ◽  
Author(s):  
Gorkem Yilmaz ◽  
Birol Iskin ◽  
Faruk Yilmaz ◽  
Yusuf Yagci
Keyword(s):  
Visible Light ◽  
Cationic Polymerization

Quinoxaline derivatives as long wavelength photosensitizers in photoinitiated cationic polymerization of diaryliodonium salts

2012 ◽  
Vol 73 (2-3) ◽  
pp. 215-218 ◽  
Author(s):  
Umut Bulut ◽  
Merve Kolay ◽  
Simge Tarkuc ◽  
Yasemin Arslan Udum ◽  
Levent Toppare
Keyword(s):  
Cationic Polymerization ◽  
Long Wavelength ◽  
Diaryliodonium Salts ◽  
Quinoxaline Derivatives

scholarly journals Coumarins as Powerful Photosensitizers for the Cationic Polymerization of Epoxy-Silicones under Near-UV and Visible Light and Applications for 3D Printing Technology

Molecules ◽  
2020 ◽  
Vol 25 (9) ◽  
pp. 2063 ◽  
Author(s):  
Mira Abdallah ◽  
Akram Hijazi ◽  
Frédéric Dumur ◽  
Jacques Lalevée
Keyword(s):  
3D Printing ◽  
Visible Light ◽  
Blue Light ◽  
Laser Diode ◽  
Cationic Polymerization ◽  
High Performance ◽  
Printing Technology ◽  
3D Printing Technology ◽  
Visible Irradiation

In this study, eight coumarins (coumarins 1–8) are proposed as near-UV and blue light sensitive photoinitiators/photosensitizers for the cationic polymerization (CP) of epoxysilicones when combined with 4-isopropyl-4’-methyldiphenyliodonium tetrakis(pentafluorophenyl)borate (IOD). Among these coumarins, four of them (coumarins 1, 2, 6 and 8) have never been reported in the literature, i.e., these structures have been specifically designed to act as photoinitiators for silicones upon near UV and visible irradiation. Good final reactive epoxy function conversions (FCs) and also high rates of polymerization (Rp) were achieved in the presence of the newly proposed coumarin-based systems. The polymers generated from the photopolymerization of epoxysilicones can be considered as attractive candidates for several applications such as: elastomers, coatings, adhesives, and so on. The goal of this study focuses also on the comparison of the new proposed coumarins with well-established photosensitizers i.e., 1-chloro-4-propoxythioxanthone (CPTX), 9,10-dibutoxyanthracene (DBA) or some commercial coumarins (Com. Coum). As example of their high performance, the new proposed coumarins were also used for laser write experiments upon irradiation with a laser diode at 405 nm in order to develop new cationic 3D printing systems.

Polyethylene-g-poly(cyclohexene oxide) by Mechanistic Transformation from ROMP to Visible Light-Induced Free Radical Promoted Cationic Polymerization

2015 ◽  
Vol 48 (6) ◽  
pp. 1658-1663 ◽  
Author(s):  
Mustafa Ciftci ◽  
Senem Kork ◽  
Guangjuan Xu ◽  
Michael R. Buchmeiser ◽  
Yusuf Yagci
Keyword(s):  
Free Radical ◽  
Visible Light ◽  
Cationic Polymerization ◽  
Cyclohexene Oxide

Metal-free photoinitiated controlled cationic polymerization of isopropyl vinyl ether using diaryliodonium salts

2019 ◽  
Vol 10 (9) ◽  
pp. 1056-1061 ◽  
Author(s):  
Tsuyoshi Nishikawa ◽  
Arihiro Kanazawa ◽  
Sadahito Aoshima
Keyword(s):  
Vinyl Ether ◽  
Cationic Polymerization ◽  
Metal Free ◽  
Diaryliodonium Salts

Metal-free photoinitiated controlled cationic polymerization of isopropyl vinyl ether proceeded via the spontaneous cleavage of the carbon–iodine bonds at the propagating ends.

scholarly journals Poly(phenylenevinylene)s as Sensitizers for Visible Light Induced Cationic Polymerization

2014 ◽  
Vol 47 (21) ◽  
pp. 7296-7302 ◽  
Author(s):  
Semih Erdur ◽  
Gorkem Yilmaz ◽  
Demet Goen Colak ◽  
Ioan Cianga ◽  
Yusuf Yagci
Keyword(s):  
Visible Light ◽  
Cationic Polymerization
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