Fluorinated Alcohols As Promoters for the Metal-Free Direct Substitution Reaction of Allylic Alcohols with Nitrogenated, Silylated, and Carbon Nucleophiles

2012 ◽  
Vol 77 (17) ◽  
pp. 7344-7354 ◽  
Author(s):  
Paz Trillo ◽  
Alejandro Baeza ◽  
Carmen Nájera
Keyword(s):  
Substitution Reaction ◽  
Allylic Alcohols ◽  
Metal Free ◽  
Carbon Nucleophiles ◽  
Fluorinated Alcohols ◽  
Direct Substitution

scholarly journals Biocompatible ionic liquid [Betaine][H2PO4] as a reusable catalyst for the substitution of xanthen-9-ol under solvent-free conditions

RSC Advances ◽  
2020 ◽  
Vol 10 (52) ◽  
pp. 31662-31669
Author(s):  
Anlian Zhu ◽  
Tong Wang ◽  
Wanlu Feng ◽  
Jianji Wang ◽  
Lingjun Li
Keyword(s):  
Ionic Liquid ◽  
Substitution Reaction ◽  
Solvent Free ◽  
Reusable Catalyst ◽  
Solvent Free Conditions ◽  
Direct Substitution

A cheap and biocompatible ionic liquid [Betaine][H2PO4] was found to be an efficient and reusable catalyst for the direct substitution reaction of xanthen-9-ol under solvent-free conditions.

ChemInform Abstract: Metal-Free Catalyzed Regioselective Allylic Trifluoromethanesulfonylation of Aromatic Allylic Alcohols with Sodium Trifluoromethanesulfinate.

ChemInform ◽  
2016 ◽  
Vol 47 (26) ◽  
Author(s):  
Jianhua Liao ◽  
Wei Guo ◽  
Zhenming Zhang ◽  
Xiaodong Tang ◽  
Wanqing Wu ◽  
...  
Keyword(s):  
Allylic Alcohols ◽  
Metal Free

Electrochemical Oxidative Cyclization of Alkenes, Boronic Acids, and Dichalcogenides to Access Chalcogenated Boronic Esters and 1,3-Diols

2021 ◽  
Author(s):  
Changfeng Huang ◽  
Jijing Hu ◽  
Guangxian Chen ◽  
Minjian Wu ◽  
Hua Cao ◽  
...  
Keyword(s):  
Boronic Acids ◽  
Oxidative Cyclization ◽  
Environmentally Benign ◽  
Allylic Alcohols ◽  
Efficient Manner ◽  
Metal Free ◽  
Boronic Esters

A sustainable, environmentally benign electrochemical oxidative three-component cyclization of allylic alcohols, boronic acids, and dichalcogenides under metal-free and oxidant-free conditions has been developed, which provides an efficient manner for the...

ChemInform Abstract: Metal-Free Oxidative C(sp3)-H Bond Functionalization of Alkanes and Alkylation-Initiated Radical 1,2-Aryl Migration in α,α-Diaryl Allylic Alcohols.

ChemInform ◽  
2015 ◽  
Vol 46 (23) ◽  
pp. no-no
Author(s):  
Jincan Zhao ◽  
Hong Fang ◽  
Ruichun Song ◽  
Jie Zhou ◽  
Jianlin Han ◽  
...  
Keyword(s):  
Allylic Alcohols ◽  
Bond Functionalization ◽  
Metal Free
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