Hydrogen-Bond-Mediated Self-Assembly of 26-Membered Diaza Tetraester Crowns of 3,5-Disubstituted 1H-Pyrazole. Dimerization Study in the Solid State and in CDCl3Solution

2011 ◽  
Vol 76 (20) ◽  
pp. 8223-8231 ◽  
Author(s):  
Felipe Reviriego ◽  
Pilar Navarro ◽  
Vicente J. Arán ◽  
Maria Luisa Jimeno ◽  
Enrique García-España ◽  
...  
CrystEngComm ◽  
2016 ◽  
Vol 18 (37) ◽  
pp. 7021-7028 ◽  
Author(s):  
Laura R. Blackholly ◽  
Helena J. Shepherd ◽  
Jennifer R. Hiscock

The effects of hydrogen bond donor acidity and counter cation within a ‘frustrated’ self-assembled, hydrogen bonded system.


2014 ◽  
Vol 70 (a1) ◽  
pp. C528-C528
Author(s):  
Leonard MacGillivray

In this presentation, we will describe our efforts to develop a general method to control chemical reactivity in the organic solid state. We use the method to provide access to complex organic molecules such as ladderanes and cyclophanes. In our method, we exploit hydrogen-bond-directed self-assembly with the use of small-molecule templates to assemble and preorganize olefins for intermolecular [2+2] photodimerizations. The templates assemble the olefins within discrete supramolecular assemblies for single and multiple photoreactions. By assembling the olefins within discrete assemblies, we overcome problems of long-range packing that have frustrated previous attempts to control the dimerization. We will also demonstrate how the approach provides a unique form of supamolecular catalysis that exploits fundamentals of mechanochemistry.


2021 ◽  
Vol 522 ◽  
pp. 120373
Author(s):  
Alexander G. Tskhovrebov ◽  
Alexander S. Novikov ◽  
Boris S. Tupertsev ◽  
Alexey A. Nazarov ◽  
Anastasia A. Antonets ◽  
...  

2003 ◽  
pp. 2834 ◽  
Author(s):  
Robin K. Harris ◽  
Phuong Y. Ghi ◽  
Robert B. Hammond ◽  
Cai-Yun Ma ◽  
Kevin J. Roberts

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