Influence of the Structure of Polyfluorinated Alcohols on Brønsted Acidity/Hydrogen-Bond Donor Ability and Consequences on the Promoter Effect

2011 ◽  
Vol 76 (4) ◽  
pp. 1126-1133 ◽  
Author(s):  
Daniela Vuluga ◽  
Julien Legros ◽  
Benoit Crousse ◽  
Alexandra M. Z. Slawin ◽  
Christian Laurence ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Brønsted Acidity ◽  
Hydrogen Bond Donor ◽  
Promoter Effect ◽  
Brönsted Acidity ◽  
Polyfluorinated Alcohols ◽  
Donor Ability

scholarly journals Fluorination as a route towards unlocking the hydrogen bond donor ability of phenolic compounds in self-assembled monolayers

CrystEngComm ◽  
2020 ◽  
Vol 22 (14) ◽  
pp. 2425-2428
Author(s):  
Harry Pinfold ◽  
Graham Pattison ◽  
Giovanni Costantini
Keyword(s):  
Hydrogen Bond ◽  
Phenolic Compounds ◽  
Building Block ◽  
Self Assembled Monolayers ◽  
Hydrogen Bond Donor ◽  
Assembled Monolayers ◽  
Donor Ability ◽  
Self Assembled ◽  
Effective Hydrogen

Fluorination turns a prototypical diphenol into an effective hydrogen-bond-donating building block for the formation of 2D phenol–pyridine cocrystals.

Bromine−AOT Charge-Transfer Complexes and Hydrogen-Bond Donor Ability of Water in AOT−isooctane−H2O Reverse Micelles and Water-in-Oil Microemulsions

1999 ◽  
Vol 103 (24) ◽  
pp. 4997-5004 ◽  
Author(s):  
Luis Garcia-Rio ◽  
Juan C. Mejuto ◽  
Renata Ciri ◽  
Iva B. Blagoeva ◽  
J. Ramon Leis ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Charge Transfer ◽  
Reverse Micelles ◽  
Charge Transfer Complexes ◽  
Hydrogen Bond Donor ◽  
Donor Ability

Linear Solvation Energy Relationship in the Reaction between Phenacyl Bromide and 2-Mercaptobenzothiazole

2009 ◽  
Vol 34 (3) ◽  
pp. 239-248 ◽  
Author(s):  
B. Ramesh ◽  
D. Vijaya Bharathi ◽  
B. Kavitha ◽  
P. Manikyamba
Keyword(s):  
Hydrogen Bond ◽  
Rate Constants ◽  
Solvation Energy ◽  
Phenacyl Bromide ◽  
Aprotic Solvents ◽  
Hydrogen Bond Donor ◽  
Linear Solvation Energy Relationship ◽  
Donor Ability ◽  
Linear Solvation Energy ◽  
Linear Solvation

The reaction between phenacyl bromide and 2-mercaptobenzothiazole was studied conductometrically in 17 different protic and aprotic solvents. The second order rate constants determined are found to be highly susceptible to changes in the solvation abilities of the solvents. Correlation of the rate constants with different solvent parameters indicated that the solvation of the reactants and the transition state is due to the electrophilicity, hydrogen bond donor ability, specific polarisability and a non-specific polarity of the solvent. by statistical analysis, a linear solvation energy relationship is derived and the percentage contributions of each type of solvation are estimated.

Theoretical investigation on the mechanism of Cu(ii)-catalyzed synthesis of 4-quinolones: effects of additives HOTf vs. HOTs

2019 ◽  
Vol 43 (10) ◽  
pp. 4291-4305 ◽  
Author(s):  
Binfang Yuan ◽  
Xiaogang Guo ◽  
Guangzhao Wang ◽  
Huisheng Huang ◽  
Fulan Zhang ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Theoretical Investigation ◽  
Proton Donor ◽  
Primary Factor ◽  
Hydrogen Bond Donor ◽  
Donor Ability

Hydrogen-bond donor/proton-donor ability is revealed to be the primary factor that controls the catalytic capability of additives (HOTf vs. HOTs).

Hydrogen-Bond Donicity in DMSO and Gas Phase and Its Dependence on Brønsted Acidity

2016 ◽  
Vol 121 (1) ◽  
pp. 357-369 ◽  
Author(s):  
Sofja Tshepelevitsh ◽  
Aleksander Trummal ◽  
Kristjan Haav ◽  
Kerli Martin ◽  
Ivo Leito
Keyword(s):  
Hydrogen Bond ◽  
Gas Phase ◽  
Brønsted Acidity ◽  
Brönsted Acidity
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