A Palladium-Catalyzed Multicomponent Synthesis of Imidazolinium Salts and Imidazolines from Imines, Acid Chlorides, and Carbon Monoxide

2011 ◽  
Vol 76 (1) ◽  
pp. 170-180 ◽  
Author(s):  
Kraig Worrall ◽  
Boran Xu ◽  
Sébastien Bontemps ◽  
Bruce A. Arndtsen
Molecules ◽  
2012 ◽  
Vol 17 (12) ◽  
pp. 13759-13768 ◽  
Author(s):  
Boran Xu ◽  
Kraig Worrall ◽  
Bruce Arndtsen

2021 ◽  
Author(s):  
Sébastien A. Roy ◽  
José Zgheib ◽  
Cuihan Zhou ◽  
Bruce A. Arndtsen

A palladium catalyzed, multicomponent synthesis of indolizines is described via the carbon monoxide driven generation of reactive, pyridine-based 1,3-dipoles.


ChemInform ◽  
2007 ◽  
Vol 38 (2) ◽  
Author(s):  
Rajiv Dhawan ◽  
Rania D. Dghaym ◽  
Daniel J. St. Cyr ◽  
Bruce A. Arndtsen

2006 ◽  
Vol 8 (18) ◽  
pp. 3927-3930 ◽  
Author(s):  
Rajiv Dhawan ◽  
Rania D. Dghaym ◽  
Daniel J. St. Cyr ◽  
Bruce A. Arndtsen

1991 ◽  
Vol 56 (3) ◽  
pp. 663-672 ◽  
Author(s):  
Curtis B. Anderson ◽  
Rade Marković

The influence of temperature and carbon monoxide pressure on the course of oxidative carbonylation reaction of 1,5-cyclooctadiene in the presence of the palladium(II) salts as a catalyst, was investigated.


Synthesis ◽  
2021 ◽  
Author(s):  
Zheng-Yang Gu ◽  
Yang Wu ◽  
Feng Jin ◽  
Bao Xiaoguang ◽  
Ji-Bao Xia

An atom- and step-economic intermolecular multi-component palladium-catalyzed C–H amidation of alkenes with carbon monoxide and organic azides has been developed for the synthesis of alkenyl amides. The reaction proceeds efficiently without an ortho-directing group on the alkene substrates. Nontoxic dinitrogen is generated as the sole by-product. Computational studies and control experiments have revealed that the reaction takes place via an unexpected mechanism by tandem palladium catalysis.


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