Palladium-Catalyzed Stereospecific Synthesis of 2,6-Disubstituted Tetrahydropyrans:  1,3-Chirality Transfer by an Intramolecular Oxypalladation Reaction

2006 ◽  
Vol 71 (12) ◽  
pp. 4530-4537 ◽  
Author(s):  
Nobuyuki Kawai ◽  
Jean-Marie Lagrange ◽  
Masashi Ohmi ◽  
Jun'ichi Uenishi
Keyword(s):  
Stereospecific Synthesis ◽  
Chirality Transfer ◽  
Palladium Catalyzed

Utilization of Sequential Palladium-Catalyzed Cross-Coupling Reactions in the Stereospecific Synthesis of Trisubstituted Olefins

2009 ◽  
Vol 13 (3) ◽  
pp. 598-606 ◽  
Author(s):  
Ioannis N. Houpis ◽  
Didier Shilds ◽  
Ulrike Nettekoven ◽  
Anita Schnyder ◽  
Erhart Bappert ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Stereospecific Synthesis ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Trisubstituted Olefins ◽  
Palladium Catalyzed

Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral Allenylsilanes and Their Application to SE2′ Chirality Transfer Reactions

2010 ◽  
Vol 12 (24) ◽  
pp. 5736-5739 ◽  
Author(s):  
Masamichi Ogasawara ◽  
Atsushi Okada ◽  
Velusamy Subbarayan ◽  
Sebastian Sörgel ◽  
Tamotsu Takahashi
Keyword(s):  
Asymmetric Synthesis ◽  
Transfer Reactions ◽  
Chirality Transfer ◽  
Axially Chiral ◽  
Palladium Catalyzed

Palladium-Catalyzed One-Pot Stereospecific Synthesis of 2-Deoxy Aryl C-Glycosides from Glycals and Anilines in the Presence of tert-Butyl Nitrite

Synthesis ◽  
2019 ◽  
Vol 51 (22) ◽  
pp. 4215-4230 ◽  
Author(s):  
Adesh Kumar Singh ◽  
Rapelly Venkatesh ◽  
Jeyakumar Kandasamy
Keyword(s):  
Room Temperature ◽  
Stereospecific Synthesis ◽  
One Pot ◽  
Tert Butyl ◽  
Mild Conditions ◽  
One Pot Synthesis ◽  
Palladium Catalyzed ◽  
Aryl Glycosides

The palladium-catalyzed one-pot synthesis of 2,3-deoxy-3-keto aryl C-glycosides is achieved from glycals and anilines in the presence of tert-butyl nitrite and aqueous HBF4 under mild conditions. This one-pot method stereospecifically provides α- and β-aryl glycosides (≥19:1 by NMR) in good yields at room temperature. The configuration at the C-3 position in the glycal determines the anomeric selectivity (i.e., α or β) of the desired products.

Stereospecific Synthesis of Chalcogenoenynes by Palladium-Catalyzed Cross-Coupling Reaction

Synlett ◽  
2003 ◽  
pp. 0579-0581 ◽  
Author(s):  
Gilson Zeni ◽  
Cristina W. Nogueira ◽  
Jesus M. Pena ◽  
Cristiane Pilissão ◽  
Paulo H. Menezes ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Stereospecific Synthesis ◽  
Cross Coupling Reaction ◽  
Palladium Catalyzed
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