Tetrasubstituted Olefin Synthesis via Pd-Catalyzed Addition of Arylboronic Acids to Internal Alkynes Using O2as an Oxidant

2006 ◽  
Vol 71 (8) ◽  
pp. 3184-3191 ◽  
Author(s):  
Chengxiang Zhou ◽  
Richard C. Larock
Keyword(s):  
Arylboronic Acids ◽  
Olefin Synthesis ◽  
Internal Alkynes

ChemInform Abstract: Copper-Catalyzed Synthesis of Internal Alkynes via Domino Coupling Between 1,1-Dihalo-1-alkenes and Arylboronic Acids.

ChemInform ◽  
2013 ◽  
Vol 44 (21) ◽  
pp. no-no
Author(s):  
Hong Yan ◽  
Linhua Lu ◽  
Peng Sun ◽  
Yan Zhu ◽  
Hailong Yang ◽  
...  
Keyword(s):  
Arylboronic Acids ◽  
Internal Alkynes

Trisubstituted olefin synthesis via Ni-catalyzed hydroalkylation of internal alkynes with non-activated alkyl halides

2018 ◽  
Vol 54 (35) ◽  
pp. 4417-4420 ◽  
Author(s):  
Xiao-Yu Lu ◽  
Mei-Lan Hong ◽  
Hai-Pin Zhou ◽  
Yue Wang ◽  
Jin-Yu Wang ◽  
...  
Keyword(s):  
Stereoselective Synthesis ◽  
Alkyl Halides ◽  
Olefin Synthesis ◽  
Internal Alkynes

The stereoselective synthesis of tri-substituted alkenes is challenging.

Hydrophenylation of internal alkynes with boronic acids catalysed by a Ni–Zn hydroxy double salt-intercalated anionic rhodium(iii) complex

2016 ◽  
Vol 6 (3) ◽  
pp. 863-868 ◽  
Author(s):  
Takayoshi Hara ◽  
Nozomi Fujita ◽  
Nobuyuki Ichikuni ◽  
Karen Wilson ◽  
Adam F. Lee ◽  
...  
Keyword(s):  
Boronic Acids ◽  
Double Salt ◽  
Basic Salt ◽  
Efficient Catalyst ◽  
Arylboronic Acids ◽  
Mild Conditions ◽  
Internal Alkynes

[Rh(OH)6]3− intercalated Ni–Zn mixed basic salt (Rh/NiZn) acts as an efficient catalyst for the hydrophenylation of internal alkynes with arylboronic acids under mild conditions.

Aggregation-Induced Emission and Photocyclization of Poly(hexaphenyl-1,3-butadiene)s Synthesized from “1 + 2” Polycoupling of Internal Alkynes and Arylboronic Acids

2016 ◽  
Vol 49 (16) ◽  
pp. 5817-5830 ◽  
Author(s):  
Yajing Liu ◽  
Jacky W. Y. Lam ◽  
Xiaoyan Zheng ◽  
Qian Peng ◽  
Ryan T. K. Kwok ◽  
...  
Keyword(s):  
Aggregation Induced Emission ◽  
Arylboronic Acids ◽  
Internal Alkynes

scholarly journals Synthesis of α,β-Unsaturated Ketones by Rhodium-Catalyzed Carbonylative Arylation of Internal Alkynes with Arylboronic Acids

Synlett ◽  
2008 ◽  
Vol 2008 (17) ◽  
pp. 2587-2592 ◽  
Author(s):  
Levent Artok ◽  
Melih Kuş ◽  
Özge Artok ◽  
Firat Ziyanak
Keyword(s):  
Unsaturated Ketones ◽  
Arylboronic Acids ◽  
Internal Alkynes
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