Remarkable Reactivity Difference in Oxygen-Substituted versus Non-Oxygen-Substituted Bromoalkynes in Cu(I)-Catalyzed Cross-Coupling Reactions:  Total Synthesis of (−)-S-18-Hydroxyminquartynoic Acid

2003 ◽  
Vol 68 (15) ◽  
pp. 5956-5960 ◽  
Author(s):  
Benjamin W. Gung ◽  
Godwin Kumi
Keyword(s):  
Total Synthesis ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

Palladium-Catalyzed Cross-Coupling Reactions in Total Synthesis

ChemInform ◽  
2005 ◽  
Vol 36 (42) ◽  
Author(s):  
K. C. Nicolaou ◽  
Paul G. Bulger ◽  
David Sarlah
Keyword(s):  
Total Synthesis ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Palladium Catalyzed

scholarly journals Total synthesis of tubastrine and 3-dehydroxy tubastrine by microwave-assisted cross-coupling reactions

Tetrahedron ◽  
2015 ◽  
Vol 71 (43) ◽  
pp. 8278-8284 ◽  
Author(s):  
Marianne Lorentzen ◽  
Annette Bayer ◽  
Magne O. Sydnes ◽  
Kåre B. Jørgensen
Keyword(s):  
Total Synthesis ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Microwave Assisted ◽  
Cross Coupling Reactions

scholarly journals Recent Advances of Pd/C-Catalyzed Reactions

Catalysts ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1078
Author(s):  
Zhenjun Mao ◽  
Haorui Gu ◽  
Xufeng Lin
Keyword(s):  
Total Synthesis ◽  
Organic Synthesis ◽  
Palladium Catalyst ◽  
Cross Coupling ◽  
Catalyst System ◽  
Coupling Reactions ◽  
Reduction Reactions ◽  
Cross Coupling Reactions ◽  
Recent Advances ◽  
Catalyzed Reactions

The Pd/C-catalyzed reactions, including reduction reactions and cross-coupling reactions, play an irreplaceable role in modern organic synthesis. Compared to the homogeneous palladium catalyst system, the heterogeneous Pd/C catalyst system offers an alternative protocol that has particular advantages and applications. Herein, a review on Pd/C-catalyzed reactions is presented. Both the advances in Pd/C-catalyzed methodologies and the application of Pd/C-catalysis in total synthesis are covered in this review.

scholarly journals Total Synthesis of Asparenydiol by Two Sonogashira Cross-Coupling Reactions Promoted by Supported Pd and Cu Catalysts

Synthesis ◽  
2020 ◽  
Vol 52 (12) ◽  
pp. 1795-1803
Author(s):  
Claudio Evangelisti ◽  
Gaetano Angelici ◽  
Gianluca Casotti ◽  
Graziano Fusini ◽  
Matteo Ferreri ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Natural Compound ◽  
Cross Coupling ◽  
Catalytic Efficiency ◽  
Coupling Reactions ◽  
Pharmacological Activities ◽  
Cross Coupling Reactions ◽  
Cu Catalysts ◽  
Supported Pd

Asparenydiol, which is an important natural compound with potential pharmacological activities, was synthesized through two Sonogashira­ cross-coupling reactions catalyzed by supported Pd and Cu catalysts and by a Mitsunobu etherification. The optimization of the Sonogashira­ couplings allowed the use of catalysts supported on different matrices with good results in terms of catalytic efficiency and yields.

Sign in / Sign up

Export Citation Format

Share Document