Highly Efficient Rhodium/Monodentate Phosphoramidite Catalyst and Its Application in the Enantioselective Hydrogenation of Enamides and α-Dehydroamino Acid Derivatives

2003 ◽  
Vol 68 (11) ◽  
pp. 4539-4541 ◽  
Author(s):  
Xian Jia ◽  
Xingshu Li ◽  
Lijin Xu ◽  
Qian Shi ◽  
Xinsheng Yao ◽  
...  
Keyword(s):  
Enantioselective Hydrogenation ◽  
Highly Efficient ◽  
Dehydroamino Acid

Air-Stable Catalysts for Highly Efficient and Enantioselective Hydrogenation of Aromatic Ketones

2002 ◽  
Vol 67 (22) ◽  
pp. 7908-7910 ◽  
Author(s):  
Jing Wu ◽  
Hua Chen ◽  
Waihim Kwok ◽  
Rongwei Guo ◽  
Zhongyuan Zhou ◽  
...  
Keyword(s):  
Enantioselective Hydrogenation ◽  
Aromatic Ketones ◽  
Highly Efficient

New unsymmetrical hybrid ferrocenylphosphine-phosphoramidite ligands derived from H8-BINOL for highly efficient Rh-catalyzed enantioselective hydrogenation

2005 ◽  
Vol 16 (6) ◽  
pp. 1233-1238 ◽  
Author(s):  
Qing-Heng Zeng ◽  
Xiang-Ping Hu ◽  
Zheng-Chao Duan ◽  
Xin-Miao Liang ◽  
Zhuo Zheng
Keyword(s):  
Enantioselective Hydrogenation ◽  
Highly Efficient

Enantioselective Hydrogenation of Cyclic Tetrasubstituted-Olefinic Dehydroamino Acid Derivatives

2021 ◽  
Author(s):  
Feng Wan ◽  
Nan Wang ◽  
Yuxin Zhu ◽  
Chuyan Tang ◽  
Jerome P Claverie ◽  
...  
Keyword(s):  
Asymmetric Hydrogenation ◽  
Enantioselective Hydrogenation ◽  
Chiral Centers ◽  
Dehydroamino Acid

Efficient asymmetric hydrogenation of cyclic tetrasubstituted-olefinic dehydroamino acid derivatives have been achieved with a Rh-ArcPhos catalyst, affording a series of α-acylamino-β-alkyl tetrahydropyranones with two contiguous chiral centers in up to...

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