scholarly journals Solid-State Molecular Folding and Supramolecular Structures of Triptycene-Derived Secondary Dicarboxamides

2002 ◽  
Vol 67 (21) ◽  
pp. 7343-7354 ◽  
Author(s):  
Jye-Shane Yang ◽  
Chia-Peng Liu ◽  
Bor-Ching Lin ◽  
Chih-Wei Tu ◽  
Gene-Hsiang Lee
Keyword(s):  
Solid State ◽  
Supramolecular Structures ◽  
Molecular Folding

Pentafluorophenyl Copper–Pyridine Complexes: Synthesis, Supramolecular Structures via Cuprophilic and π-Stacking Interactions, and Solid-State Luminescence

2011 ◽  
Vol 31 (4) ◽  
pp. 1546-1558 ◽  
Author(s):  
Ami Doshi ◽  
Anand Sundararaman ◽  
Krishnan Venkatasubbaiah ◽  
Lev N. Zakharov ◽  
Arnold L. Rheingold ◽  
...  
Keyword(s):  
Solid State ◽  
Supramolecular Structures ◽  
Stacking Interactions ◽  
Pyridine Complexes ◽  
Π Stacking ◽  
State Luminescence

scholarly journals Exploring the Self-Assembled Tacticity in Aurophilic Polymeric Arrangements of Diphosphanegold(I) Fluorothiolates

Molecules ◽  
2019 ◽  
Vol 24 (23) ◽  
pp. 4422 ◽  
Author(s):  
Moreno-Alcántar ◽  
Salazar ◽  
Romo-Islas ◽  
Flores-Álamo ◽  
Torrens
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Structural Diversity ◽  
Supramolecular Structures ◽  
X Ray Diffraction ◽  
Ligand Effects ◽  
Rational Control ◽  
Solid State Structures ◽  
Further Development ◽  
Aurophilic Interactions

Despite the recurrence of aurophilic interactions in the solid-state structures of gold(I) compounds, its rational control, modulation, and application in the generation of functional supramolecular structures is an area that requires further development. The ligand effects over the aurophilic-based supramolecular structures need to be better understood. This paper presents the supramolecular structural diversity of a series of new 1,3-bis(diphenylphosphane)propane (dppp) gold(I) fluorinated thiolates with the general formula [Au2(SRF)2(μ-dppp)] (SRF = SC6F5 (1); SC6HF4-4 (2); SC6H3(CF3)2-3,5 (3); SC6H4CF3-2 (4); SC6H4CF3-4 (5); SC6H3F2-3,4 (6); SC6H3F2-3,5 (7); SC6H4F-2 (8); SC6H4F-3 (9); SC6H4F-4 (10)). These compounds were synthesized and characterized, and six of their solid-state crystalline structures were determined using single-crystal X-ray diffraction. In the crystalline arrangement, they form aurophilic-bridged polymers. In these systems, the changes in the fluorination patterns of the thiolate ligands tune the aurophilic-induced self-assembly of the compounds causing tacticity and chiral differentiation of the monomers. This is an example of the use of ligand effects on the tune of the supramolecular association of gold complexes.

Self-Assembly of Pentaphenol Adducts:  Formation of 3D Network and Ladder-type Supramolecular Structures in the Solid State

2006 ◽  
Vol 6 (3) ◽  
pp. 636-642 ◽  
Author(s):  
Akhila Jayaraman ◽  
Venkataramanan Balasubramaniam ◽  
Suresh Valiyaveettil
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Supramolecular Structures ◽  
3D Network

scholarly journals Hydrogen-Bonded Networks Based on Cobalt(II), Nickel(II), and Zinc(II) Complexes of N,N'-Diethylurea

2010 ◽  
Vol 2010 ◽  
pp. 1-12 ◽  
Author(s):  
Labrini Drakopoulou ◽  
Catherine P. Raptopoulou ◽  
Aris Terzis ◽  
Giannis S. Papaefstathiou
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Hydrogen Bonds ◽  
Vibrational Spectroscopy ◽  
Supramolecular Structures ◽  
Counter Ion ◽  
Structure Determinations ◽  
Hydrogen Bonded

N,N'-diethylurea (DEU) was employed as a ligand to form the octahedral complexes[M(DEU)6]2+(M=Co, Ni and Zn). Compounds[Co(DEU)6](BF4)2(1),[Co(DEU)6](CIO4)2(2),[Ni(DEU)6](CIO4)2(3), and[Zn(DMU)6](CIO4)2(4) have been prepared from the reactions of DEU and the appropriate hydrated metal(II) salts in EtOH in the presence of 2,2-dimethoxypropane. Crystal structure determinations demonstrate the existence of[M(DEU)6]2+cations andCIO4-(in2–4) orBF4-(in1) counterions. The[M(DEU)6]2+cations in the solid state are stabilized by apseudochelateeffect due to the existence of six strong intracationicN-H⋯O(DEU)hydrogen bonds. The[M(DEU)6]2+cations and counterions self-assemble to form hydrogen-bonded 2D architectures in2–4that conform to thekgd(kagome dual) network, and a 3D hydrogen-bondedrtl(rutile) network in1. The nature of the resulting supramolecular structures is influenced by the nature of the counter-ion. The complexes were also characterized by vibrational spectroscopy (IR).

Solid-state supramolecular structures and excellent photothermal activities of dimeric zinc(II) phthalocyanines axially bridged with bipyridine derivatives

2021 ◽  
pp. 110037
Author(s):  
Yan Zhao ◽  
Kun-Qi Zou ◽  
Wen-Xu Zheng ◽  
Chang-Cang Huang ◽  
Bi-Yuan Zheng ◽  
...  
Keyword(s):  
Solid State ◽  
Supramolecular Structures

scholarly journals Self-assembled supramolecular structures of O,N,N′ tridentate imidazole–phenol Schiff base compounds

RSC Advances ◽  
2020 ◽  
Vol 10 (13) ◽  
pp. 7867-7878
Author(s):  
Kristy-Lyn Barry ◽  
Craig D. Grimmer ◽  
Orde Q. Munro ◽  
Matthew P. Akerman
Keyword(s):  
Schiff Base ◽  
Solid State ◽  
Supramolecular Structures ◽  
Solution State ◽  
Imidazole Group ◽  
Methyl Imidazole ◽  
Self Assembled ◽  
Imine Bond ◽  
Phenol Ring

Three imidazole-derived Schiff base compounds comprising an N-methyl imidazole group coupled to a phenol ring through an imine bond were synthesised. The solid state and solution state supramolecular structures as well as energetics are explored.

Solid-State Supramolecular Structures of Resorcinol−Arylboronic Acid Compounds

2001 ◽  
Vol 3 (16) ◽  
pp. 2443-2445 ◽  
Author(s):  
Claude J. Davis ◽  
Patrick T. Lewis ◽  
Damon R. Billodeaux ◽  
Frank R. Fronczek ◽  
Jorge O. Escobedo ◽  
...  
Keyword(s):  
Solid State ◽  
Supramolecular Structures ◽  
Arylboronic Acid
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