Highly convenient electrolysis procedure for the preparation of .alpha.-halogenated ketones and acetals from enol acetates, enol ethers, and silyl enol ethers

Sigeru Torii; Tsutomu Inokuchi; Seiji Mishima; Takesi Kobayashi

doi:10.1021/jo01301a044

Highly convenient electrolysis procedure for the preparation of .alpha.-halogenated ketones and acetals from enol acetates, enol ethers, and silyl enol ethers

The Journal of Organic Chemistry ◽

10.1021/jo01301a044 ◽

1980 ◽

Vol 45 (13) ◽

pp. 2731-2735 ◽

Cited By ~ 26

Author(s):

Sigeru Torii ◽

Tsutomu Inokuchi ◽

Seiji Mishima ◽

Takesi Kobayashi

Keyword(s):

Enol Ethers ◽

Silyl Enol Ethers ◽

Enol Acetates

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New synthetic methods for α,β -unsaturated ketones, aldehydes, esters and lactones by the palladium-catalyzed reactions of silyl enol ethers, ketene silyl acetals, and enol acetates with allyl carbonates

Tetrahedron ◽

10.1016/s0040-4020(01)90587-3 ◽

1986 ◽

Vol 42 (11) ◽

pp. 2971-2977 ◽

Cited By ~ 86

Author(s):

Ichiro Minami ◽

Kazuhiko Takahashi ◽

Isao Shimizu ◽

Tsuneo Kimura ◽

Jiro Tsuji

Keyword(s):

Synthetic Methods ◽

Enol Ethers ◽

Unsaturated Ketones ◽

Silyl Enol Ethers ◽

Palladium Catalyzed ◽

Enol Acetates ◽

Silyl Acetals ◽

Catalyzed Reactions

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ChemInform Abstract: Alkoxide-Mediated Preparation of Enolates from Silyl Enol Ethers and Enol Acetates - From Discovery to Synthetic Applications

ChemInform ◽

10.1002/chin.200204270 ◽

2010 ◽

Vol 33 (4) ◽

pp. no-no

Author(s):

Dominique Cahard ◽

Pierre Duhamel ◽

et al. et al.

Keyword(s):

Enol Ethers ◽

Silyl Enol Ethers ◽

Enol Acetates

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ChemInform Abstract: New Synthetic Methods for α,β-Unsaturated Ketones, Aldehydes, Esters and Lactones by the Palladium-catalyzed Reactions of Silyl Enol Ethers, Ketene Silyl Acetals, and Enol Acetates with Allyl Carbonates.

Chemischer Informationsdienst ◽

10.1002/chin.198641173 ◽

1986 ◽

Vol 17 (41) ◽

Author(s):

I. MINAMI ◽

K. TAKAHASHI ◽

I. SHIMIZU ◽

T. KIMURA ◽

J. TSUJI

Keyword(s):

Synthetic Methods ◽

Enol Ethers ◽

Unsaturated Ketones ◽

Silyl Enol Ethers ◽

Palladium Catalyzed ◽

Enol Acetates ◽

Silyl Acetals ◽

Catalyzed Reactions

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Unprecedented route to enolates from silyl enol ethers and enol acetates: reaction with hard and soft electrophiles

Journal of the Chemical Society Perkin Transactions 1 ◽

10.1039/p19930002509 ◽

1993 ◽

pp. 2509 ◽

Cited By ~ 22

Author(s):

Pierre Duhamel ◽

Dominique Cahard ◽

Jean-Marie Poirier

Keyword(s):

Enol Ethers ◽

Silyl Enol Ethers ◽

Enol Acetates ◽

Soft Electrophiles

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ChemInform Abstract: ENONE FORMATION FROM ALLYL β-KETO ESTERS, ALKENYL ALLYL CARBONATES, SILYL ENOL ETHERS, AND ENOL ACETATES BY THE PHOSPHINE-FREE PALLADIUM CATALYST

Chemischer Informationsdienst ◽

10.1002/chin.198503164 ◽

1985 ◽

Vol 16 (3) ◽

Author(s):

J. TSUJI ◽

I. MINAMI ◽

I. SHIMIZU ◽

H. KATAOKA

Keyword(s):

Palladium Catalyst ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Keto Esters ◽

Enol Acetates

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ChemInform Abstract: Unprecedented Route to Enolates from Silyl Enol Ethers and Enol Acetates: Reaction with Hard and Soft Electrophiles.

ChemInform ◽

10.1002/chin.199406075 ◽

2010 ◽

Vol 25 (6) ◽

pp. no-no

Author(s):

P. DUHAMEL ◽

D. CAHARD ◽

J.-M. POIRIER

Keyword(s):

Enol Ethers ◽

Silyl Enol Ethers ◽

Enol Acetates ◽

Soft Electrophiles

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ENONE FORMATION FROM ALLYL β-KETO ESTERS, ALKENYL ALLYL CARBONATES, SILYL ENOL ETHERS, AND ENOL ACETATES BY THE PHOSPHINE-FREE PALLADIUM CATALYST

Chemistry Letters ◽

10.1246/cl.1984.1133 ◽

1984 ◽

Vol 13 (7) ◽

pp. 1133-1136 ◽

Cited By ~ 37

Author(s):

Jiro Tsuji ◽

Ichiro Minami ◽

Isao Shimizu ◽

Hideaki Kataoka

Keyword(s):

Palladium Catalyst ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Keto Esters ◽

Enol Acetates

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Radical promoted cyclisations of trichloroacetamides with silyl enol ethers and enol acetates: the role of the hydride reagent [tris(trimethylsilyl)silane vs. tributylstannane]

Journal of the Chemical Society Perkin Transactions 1 ◽

10.1039/a900952c ◽

1999 ◽

pp. 1157-1162 ◽

Cited By ~ 25

Author(s):

Josefina Quirante ◽

Carmen Escolano ◽

Faïza Diaba ◽

Josep Bonjoch

Keyword(s):

Enol Ethers ◽

Silyl Enol Ethers ◽

Enol Acetates

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Alkoxide-Mediated Preparation of Enolates from Silyl Enol Ethers and Enol Acetates − From Discovery to Synthetic Applications

European Journal of Organic Chemistry ◽

10.1002/1099-0690(200103)2001:6<1023::aid-ejoc1023>3.0.co;2-y ◽

2001 ◽

Vol 2001 (6) ◽

pp. 1023-1031 ◽

Cited By ~ 16

Author(s):

Dominique Cahard ◽

Pierre Duhamel

Keyword(s):

Enol Ethers ◽

Silyl Enol Ethers ◽

Enol Acetates

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ChemInform Abstract: HIGHLY CONVENIENT ELECTROLYSIS PROCEDURE FOR THE PREPARATION OF α-HALOGENATED KETONES AND ACETALS FROM ENOL ACETATES, ENOL ETHERS, AND SILYL ENOL ETHERS

Chemischer Informationsdienst ◽

10.1002/chin.198047090 ◽

1980 ◽

Vol 11 (47) ◽

Author(s):

S. TORII ◽

T. INOKUCHI ◽

S. MISIMA ◽

T. KOBAYASHI

Keyword(s):

Enol Ethers ◽

Silyl Enol Ethers ◽

Enol Acetates

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