The formation of 1,6-bis(trichlorosilyl)hexane by the chloroplatinic acid catalyzed hydrosilylation of 1-hexyne

1967 ◽  
Vol 32 (8) ◽  
pp. 2634-2636 ◽  
Author(s):  
Robert A. Benkeser ◽  
Robert F. Cunico ◽  
Stanley Dunny ◽  
Paul Ronald Jones ◽  
Prabhakar G. Nerlekar
Keyword(s):  
Chloroplatinic Acid ◽  
Acid Catalyzed

The Chloroplatinic Acid Catalyzed Addition of Trimethylgermanium Hydride to Dienes1

1966 ◽  
Vol 31 (8) ◽  
pp. 2445-2450 ◽  
Author(s):  
Richard H. Fish ◽  
Henry G. Kuivila
Keyword(s):  
Chloroplatinic Acid ◽  
Acid Catalyzed

ChemInform Abstract: CHLOROPLATINIC ACID CATALYZED ADDITIONS OF SILANES TO ISOPRENE

1979 ◽  
Vol 10 (1) ◽  
Author(s):  
R. A. BENKESER ◽  
F. M. II MERRITT ◽  
R. T. ROCHE
Keyword(s):  
Chloroplatinic Acid ◽  
Acid Catalyzed

scholarly journals Mechanism of Chloroplatinic acid Catalyzed Reduction of Alkyl Halides by Hydrosilanes

1969 ◽  
Vol 27 (9) ◽  
pp. 845-851
Author(s):  
Yoichiro NAGAI ◽  
Hideyuki MATSUMOTO ◽  
Tomio YAGIHARA ◽  
Katsushi MORISHITA
Keyword(s):  
Alkyl Halides ◽  
Chloroplatinic Acid ◽  
Acid Catalyzed

scholarly journals Chloroplatinic Acid-catalyzed Reduction of Haloalkanes

1969 ◽  
Vol 27 (8) ◽  
pp. 747-753 ◽  
Author(s):  
Yoichiro NAGAI ◽  
Hideyuki MATSUMOTO ◽  
Tomio YAGIHARA ◽  
Katsushi MORISHITA
Keyword(s):  
Chloroplatinic Acid ◽  
Acid Catalyzed

Chloroplatinic acid catalyzed additions of silanes to isoprene

1978 ◽  
Vol 156 (1) ◽  
pp. 235-244 ◽  
Author(s):  
Robert A. Benkeser ◽  
Frederick M. Merritt ◽  
Robert T. Roche
Keyword(s):  
Chloroplatinic Acid ◽  
Acid Catalyzed

Hydrosilylation of dialkenyl sulphides

1979 ◽  
Vol 44 (3) ◽  
pp. 742-749 ◽  
Author(s):  
Michail G. Voronkov ◽  
Václav Chvalovský ◽  
Svetlana V. Kirpichenko ◽  
Natalia N. Vlasova ◽  
Sergei T. Bolshakov ◽  
...  
Keyword(s):  
Double Bond ◽  
Rhodium Catalyst ◽  
Main Reaction ◽  
Side Reactions ◽  
Chloroplatinic Acid ◽  
Silicon Hydride ◽  
Reaction Route ◽  
Acid Catalyzed

Hydrosilylation of divinyl and diallyl sulphide by triethyl- and triethoxysilane catalyzed by H2PtCl6.6 H2O and [RhCl{P(C6H5)3}3] has been studied. With divinyl sulphide the addition of X3SiH (X = C2H5 or OC2H5) across the double bond proceeded to a negligible extent, the main reaction route being the cleavage of the =CH-S bond. The course of the reaction of diallyl sulphide depended strongly upon the catalyst and the starting silicon hydride. In the presence of both catalysts triethoxysilane adds to diallyl sulphide to form a mixture of both isomeric monoadducts (β and γ) in relative amounts depending upon the catalyst. Contrary to this, the γ-adduct is formed solely in the chloroplatinic acid catalyzed hydrosilylation of the above compound by triethylsilane whereas the cleavage of the C-S bond is predominant reaction in the presence of the rhodium catalyst. Some further side reactions are also reported.

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