Aluminum Chloride-Catalyzed Formation of 2,5-Dichloro-2,5-dimethylhexane fromtert-Butyl Chloride

1956 ◽  
Vol 21 (7) ◽  
pp. 761-763 ◽  
Author(s):  
F. E. CONDON
Keyword(s):  
Aluminum Chloride ◽  
Butyl Chloride

THE TERTIARYBUTYLBENZENES: I. ALKYLATION OF 1,4-DI-t-BUTYLBENZENE WITH t-BUTYL CHLORIDE

1955 ◽  
Vol 33 (4) ◽  
pp. 672-678 ◽  
Author(s):  
L. Ross C. Barclay ◽  
Eileen E. Betts
Keyword(s):  
Aromatic Hydrocarbon ◽  
Aluminum Chloride ◽  
Butyl Chloride ◽  
Improved Method ◽  
Alkylation Of Benzene ◽  
Amino Derivatives

The alkylation of P-di-t-butylbenzene with excess t-butyl chloride in the presence of aluminum chloride in the cold produces a new aromatic hydrocarbon, m.p. 218.5–219°. Evidence is given for the presence of an alicyclic nucleus in this hydrocarbon which analyzes for C22H34. The preparation of nitro and amino derivatives from this hydrocarbon is described. The alkylation of benzene under similar conditions yielded some 1,3,5-tri-t-butylbenzene, and an improved method of preparation of this hydrocarbon from P-di-t-butylbenzene is given.

scholarly journals tert.-Butylation of Toluene: A Statistical Study

1970 ◽  
Vol 43 (4) ◽  
pp. 545-552
Author(s):  
Mohammad Ismail ◽  
Mohammad Abu Hanif ◽  
Mirza Galib ◽  
Manoranjan Saha
Keyword(s):  
Statistical Model ◽  
Aluminum Chloride ◽  
Molar Ratio ◽  
Butyl Chloride ◽  
Anhydrous Aluminum Chloride ◽  
Tert Butyl ◽  
Catalyst Temperature ◽  
Experimental Yield ◽  
The Difference ◽  
Tert Butyl Chloride

A statistical model was developed for the alkylation of toluene with tert.-butyl chloride in presence of anhydrous aluminum chloride as catalyst. Temperature, molar ratio of toluene to tert.-butyl chloride and amount of anhydrous aluminum chloride were chosen for investigation. A set of trials was planned according to a 3 factor 2-level Yates pattern experimental design with 2 replicates and the center point trial with 4 replicates. The critical response was the yield of tert.-butyl toluene. Two- and three-factor interaction effects together with the main effects were statistically significant. The adequacy of the suggested model was checked up. The difference between the experimental and predicted yields did not exceed 2.22%. The best yield of the tert.-butyl toluene was 51.2%. Key words: tert. Butylation, Yates pattern, Experimental yield, Statistical model.     doi: 10.3329/bjsir.v43i4.2245 Bangladesh J. Sci. Ind. Res. 43(4), 545-552, 2008

THE SYNTHESIS OF ALKYLPHOSPHONOUS DICHLORIDES FROM ALUMINUM CHLORIDE – PHOSPHORUS TRICHLORIDE – ALKYL CHLORIDE COMPLEXES

1963 ◽  
Vol 41 (9) ◽  
pp. 2299-2302 ◽  
Author(s):  
B. J. Perry ◽  
J. B. Reesor ◽  
J. L. Ferron
Keyword(s):  
Aluminum Chloride ◽  
Good Yield ◽  
Methyl Chloride ◽  
Chloride Complex ◽  
Phosphorus Trichloride ◽  
High Yield ◽  
Alkyl Chloride ◽  
Butyl Chloride ◽  
Chloride Complexes ◽  
General Method

In 1957, a new method for the synthesis of methylphosphonous dichloride, in high yield, by the reduction of the aluminum chloride – phosphorus trichloride – methyl chloride complex in diethyl phthalate solution by finely powdered antimony, was developed. That this is a general method for the synthesis of the more volatile alkylphosphonous dichlorides was demonstrated by the preparation, in good yield, of a series of compounds from the aluminum chloride – phosphorus trichloride complexes formed from ethyl chloride, n-propyl chloride, i-propyl chloride, n-butyl chloride, and s-butyl chloride. As expected, isomerization occurred in the case of the normal alkyl chlorides.

tert-Butyl Chloride-Aluminum Chloride

2001 ◽  
Author(s):  
George A. Olah ◽  
G. K. Surya Prakash ◽  
Qi Wang ◽  
Xing-ya Li
Keyword(s):  
Aluminum Chloride ◽  
Butyl Chloride ◽  
Tert Butyl ◽  
Tert Butyl Chloride

THE SYNTHESIS OF SOME STEREOISOMERIC DERIVATIVES OF DECAHYDRONAPHTHALENE

1951 ◽  
Vol 29 (2) ◽  
pp. 162-165 ◽  
Author(s):  
A. Zlatkis ◽  
E. A. Smith
Keyword(s):  
Aluminum Chloride ◽  
Pure Form ◽  
New Method ◽  
High Yield ◽  
Butyl Chloride ◽  
Anhydrous Aluminum Chloride ◽  
Ethylmagnesium Bromide ◽  
Tertiary Butyl ◽  
Derivatives Of ◽  
Made In

Both racemic forms of trans 2-chlorodecalin have been prepared and separated in pure form. The reaction between these chlorodecalins and ethylmagnesium bromide has been studied and two racemates of trans 2-ethyl decalin have been isolated. Some progress has been made in the preparation of the 9-chlorodecalins. A new method for converting cis decalin to trans decalin rapidly in high yield using tertiary butyl chloride and anhydrous aluminum chloride is indicated.

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