The Mass Spectra of Organic Molecules. The Rearrangement of Acetylenic Ethers under Electron Impact

1964 ◽  
Vol 29 (10) ◽  
pp. 3024-3028 ◽  
Author(s):  
P. E. Butler
Keyword(s):  
Electron Impact ◽  
Mass Spectra ◽  
Organic Molecules

The fragmentation of organic molecules under electron-impact—III: The mass spectra of some substituted thioureas

1970 ◽  
Vol 4 (S1) ◽  
pp. 81-88 ◽  
Author(s):  
M. A. Baldwin ◽  
Alicja M. Kirkien ◽  
A. G. Loudon ◽  
Allan Maccoll
Keyword(s):  
Electron Impact ◽  
Mass Spectra ◽  
Organic Molecules

The fragmentation of organic molecules under electron-IMPACT—II. The mass spectra of tetronic acid and some of its derivatives

1968 ◽  
Vol 1 (6) ◽  
pp. 743-759 ◽  
Author(s):  
L. J. Haynes ◽  
Alicja Kirkien-Konasiewicz ◽  
A. G. Loudon ◽  
Allan Maccoll
Keyword(s):  
Electron Impact ◽  
Mass Spectra ◽  
Organic Molecules ◽  
Tetronic Acid

Mass spectra of 4,4-dimethyl-A-homo-4a,6-cholestadien-3-ols, 4,4-dimethyl-A-homo-5-cholestene-3,4a-diols and their derivatives

1982 ◽  
Vol 47 (10) ◽  
pp. 2768-2778
Author(s):  
Antonín Trka ◽  
Helena Velgová
Keyword(s):  
Carbon Atom ◽  
Electron Impact ◽  
Mass Spectra ◽  
Molecular Ions

Partial electron impact induced mass spectra are given of 3α-hydroxy-, 3β-hydroxy-, 3β-methoxy-, 3α-acetoxy- and 3β-acetoxy-4,4-dimethyl-A-homo-4a,6-cholestadienes, 3α,5α-epoxy-4,4-dimethyl-A-homo-5-cholestane, isomeric 4,4-dimethyl-A-homo-5-cholestene-3α(β),4aα(β)-diols, their 3-acetoxy derivatives and 3-methyl ethers. The fragmentation of the molecular ions of these substances involves the usual elimination of substituents (in the form of H2O, CH3OH, CH3COOH, CH2CO), but the most abundant and characteristic ions are products of the contraction of ring A (to a six- or five-membered one), accompanied by expulsion of a fragment containing the carbon atom C(4) with both methyls.

scholarly journals MASS SPECTRA OF SOME FUROQUINOLINE ALKALOIDS

1965 ◽  
Vol 43 (9) ◽  
pp. 2516-2521 ◽  
Author(s):  
D. M. Clugston ◽  
D. B. Maclean
Keyword(s):  
Electron Impact ◽  
Mass Spectra ◽  
The Other ◽  
Methoxyl Group ◽  
Quinoline Ring

The mass spectra of six furoquinoline alkaloids have been recorded and mechanisms have been proposed for their fragmentation upon electron impact. Strong metastable peaks, present in all spectra, have aided in the interpretation of the fragmentation of these alkaloids. The three alkaloids with a methoxyl group in the 8-position of the quinoline ring may be differentiated from the other three by the presence of relatively intense peaks at M-1 and M-29.

Electron impact studies. VI. Mass spectra of esters and thioesters. Skeletal rearrangement on electron impact

1967 ◽  
Vol 20 (4) ◽  
pp. 689 ◽  
Author(s):  
JH Bowie ◽  
RG Cooks ◽  
P Jakobsen ◽  
S Lawesson ◽  
G Schroll
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
High Resolution ◽  
Electron Impact ◽  
Mass Spectra ◽  
Skeletal Rearrangement ◽  
Unsaturated Esters ◽  
Impact Studies ◽  
Unsaturated Alcohols ◽  
Metastable Ions

The mass spectra of representative series of simple alkyl acetoacetates, alkyl acetothioacetates, and some unsaturated esters derived from unsaturated alcohols or phenols are reported and discussed. The fragmentation schemes have been established by high resolution measurements, appropriate metastable ions, and by deuterium and 18O labelling. Many of the spectra show significant skeletal rearrangement fragments arising from either loss of carbon monoxide or carbon dioxide.

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