Phosphorylation via Oxidation of Phosphites. I. Preparation of Dialkyl Phosphites by the Reaction of Alcohols with Ethyl N-Phenylimino Phosphite and Benzaldehyde

1964 ◽  
Vol 29 (10) ◽  
pp. 3005-3006 ◽  
Author(s):  
Oyo Mitsunobu ◽  
Teruaki Mukaiyama
Keyword(s):  
Dialkyl Phosphites

Synthesis of Phosphonates, Phosphinates and Tertiary Phosphine Oxides by Pd- or Ni-Catalyzed Microwave-Assisted P–C Coupling Reactions without the Addition of Conventional Ligands

2021 ◽  
Vol 25 ◽  
Author(s):  
Réka Henyecz ◽  
György Keglevich
Keyword(s):  
Tautomeric Form ◽  
Catalyst Precursor ◽  
Coupling Reactions ◽  
Optimum Conditions ◽  
Pd Catalysts ◽  
Catalyst Complex ◽  
Two Factors ◽  
Dialkyl Phosphites ◽  
Catalyst Systems ◽  
P Ligands

Abstract: Microwave (MW)-assistance may be a powerful tool also in the Hirao P–C coupling reactions of vinyl/aryl halides with dialkyl phosphites in the presence of Pd-catalysts/P-ligands elaborated forty years ago. This review surveys the development of this reaction by showing the expansion of the reagents and catalysts, as well as the information accumulated. The stress was laid on the “green” aspects, the simplification of the catalyst systems, and the reliable mechanistic details in order to be able to establish the optimum conditions. The best protocol involves the use of some excess of the >P(O)H reagent to ensure the PdII→Pd0 reduction and, via its trivalent tautomeric form (>POH) also the P-ligand. The overall rate is the result of two factors, the activity of the catalyst complex formed, and the reactivity of the reactants in the P–C coupling reactions. Both components are influenced by the nature of the aryl substituents in Ar2P(O)H. NiII salts may also be used as the catalyst precursor, however, despite the PdII→Pd0→PdII route, in this case, a NiII→NiIV→NiII sequence was proved.

Phosphonation of Arenes with Dialkyl Phosphites Catalyzed by Mn(II)/Co(II)/O2Redox Couple

2006 ◽  
Vol 8 (3) ◽  
pp. 407-409 ◽  
Author(s):  
Takashi Kagayama ◽  
Atsushi Nakano ◽  
Satoshi Sakaguchi ◽  
Yasutaka Ishii
Keyword(s):  
Dialkyl Phosphites

ChemInform Abstract: REACTION OF HEXAFLUOROACETONE N-BENZENESULFONYLIMINE WITH DIALKYL PHOSPHITES

1982 ◽  
Vol 13 (8) ◽  
Author(s):  
G. F. IL'IN ◽  
A. F. KOLOMIETS ◽  
G. A. SOKOL'SKII
Keyword(s):  
Dialkyl Phosphites

ChemInform Abstract: Reaction of Diphenylguanidine (I) with Dialkyl Phosphites (II).

ChemInform ◽  
2010 ◽  
Vol 22 (17) ◽  
pp. no-no
Author(s):  
S. V. FRIDLAND ◽  
I. G. SHAIKHIEV ◽  
A. A. MUKHUTDINOV ◽  
A. V. IL'YASOV ◽  
R. Z. MUSIN
Keyword(s):  
Dialkyl Phosphites

The Catalyst-free Addition of Dialkyl Phosphites on the Triple Bond of Alkyl Phenylpropiolates Under Microwave Conditions

2015 ◽  
Vol 4 (1) ◽  
pp. 57-64 ◽  
Author(s):  
Erika Balint ◽  
Judit Takacs ◽  
Maria Balint ◽  
Gyorgy Keglevich
Keyword(s):  
Triple Bond ◽  
Catalyst Free ◽  
Dialkyl Phosphites

Theoretical and Experimental Investigation of Reactions between Dialkyl Phosphites and tert-Butylphosphaethyne

2004 ◽  
Vol 40 (8) ◽  
pp. 1076-1079 ◽  
Author(s):  
E. A. Ishmaeva ◽  
E. V. Popova ◽  
V. F. Mironov ◽  
R. M. Aminova ◽  
Ya. A. Vereshchagina ◽  
...  
Keyword(s):  
Experimental Investigation ◽  
Dialkyl Phosphites

Stereochemistry of the addition of dialkyl phosphites to (S)-N,N-dibenzylphenylglycinal

2001 ◽  
Vol 12 (21) ◽  
pp. 2977-2984 ◽  
Author(s):  
Andrzej E. Wróblewski ◽  
Dorota G. Piotrowska
Keyword(s):  
Dialkyl Phosphites

Highly Regio- and Stereoselective Nickel-Catalyzed Addition of Dialkyl Phosphites to Ynamides: an Efficient Synthesis of β-Aminovinylphosphonates

2011 ◽  
Vol 353 (2-3) ◽  
pp. 263-267 ◽  
Author(s):  
Antoine Fadel ◽  
Frédéric Legrand ◽  
Gwilherm Evano ◽  
Nicolas Rabasso
Keyword(s):  
Efficient Synthesis ◽  
Dialkyl Phosphites
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