Zwitterion Radicals and Anion Radicals from Electron Transfer and Solvent Condensation with the Fingerprint Developing Agent Ninhydrin

2001 ◽  
Vol 66 (23) ◽  
pp. 7596-7603 ◽  
Author(s):  
Tyler D. Schertz ◽  
Richard C. Reiter ◽  
Cheryl D. Stevenson
Keyword(s):  
Electron Transfer ◽  
Anion Radicals

Intramolecular electron transfer and dehalogenation of nitroaromatic anion radicals

1983 ◽  
Vol 105 (3) ◽  
pp. 320-324 ◽  
Author(s):  
J. P. Bays ◽  
S. T. Blumer ◽  
S. Baral-Tosh ◽  
D. Behar ◽  
P. Netav
Keyword(s):  
Electron Transfer ◽  
Intramolecular Electron Transfer ◽  
Anion Radicals

The Electroreduction of Substituted Benzofurazans

1972 ◽  
Vol 50 (2) ◽  
pp. 263-269 ◽  
Author(s):  
W. R. Fawcett ◽  
P. A. Forte ◽  
R. O. Loutfy ◽  
J. M. Prokipcak
Keyword(s):  
Electron Transfer ◽  
Molecular Orbital ◽  
Double Layer ◽  
Rate Constants ◽  
Hyperfine Splitting ◽  
Platinum Electrode ◽  
Hückel Theory ◽  
Layer Effect ◽  
Standard Rate ◽  
Anion Radicals

The electroreduction of 4- and 5-substituted benzofurazans was investigated at a platinum electrode in acetonitrile. Standard potentials for the reactions were linearly related to the energy of the lowest vacant molecular orbital as estimated by Hückel theory. Standard rate constants for electron transfer decreased as standard potentials in the series became more cathodic. This decrease is attributed to a double layer effect. No correlation was obtained between standard rate constants and observed hyperfine splitting constants for the anion radicals.

scholarly journals Nucleophilic displacement versus electron transfer in the reactions of alkyl chlorosilanes with electrogenerated aromatic anion radicals

2015 ◽  
Vol 158 ◽  
pp. 457-469 ◽  
Author(s):  
Saida Soualmi ◽  
Mamadou Dieng ◽  
Ali Ourari ◽  
Diariatou Gningue-Sall ◽  
Viatcheslav Jouikov
Keyword(s):  
Electron Transfer ◽  
Nucleophilic Displacement ◽  
Anion Radicals

ChemInform Abstract: INTRAMOLECULAR ELECTRON TRANSFER AND DEHALOGENATION OF NITROAROMATIC ANION RADICALS

1983 ◽  
Vol 14 (21) ◽  
Author(s):  
J. P. BAYS ◽  
S. T. BLUMER ◽  
S. BARAL-TOSH ◽  
D. BEHAR ◽  
P. NETA
Keyword(s):  
Electron Transfer ◽  
Intramolecular Electron Transfer ◽  
Anion Radicals
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