Reduction of Organic Compounds by Carbon Monoxide. I. The Reductive Coupling of Aromatic Nitro Compounds1

1965 ◽  
Vol 30 (6) ◽  
pp. 2014-2020 ◽  
Author(s):  
James E. Kmiecik
Keyword(s):  
Carbon Monoxide ◽  
Organic Compounds ◽  
Reductive Coupling ◽  
Aromatic Nitro

The thermal degradation of μ-Diphenylacetylene-bis(tricarbonylcobalt)

1973 ◽  
Vol 26 (8) ◽  
pp. 1791 ◽  
Author(s):  
RS Dickson ◽  
LJ Michel
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermal Decomposition ◽  
Carbon Monoxide ◽  
Thermal Degradation ◽  
Organic Compounds ◽  
Degradation Mechanism ◽  
Scanning Calorimetry ◽  
Organic Products ◽  
Suitable Temperature ◽  
Degradation Reaction

The thermal decomposition of Co2(CO)6(PhC2Ph) has been investigated in detail. Differential scanning calorimetry was used to determine the most suitable temperature range for the study. At 180�, Co2(CO)6(PhC2Ph) decomposes to form cobalt, carbon monoxide, tetraphenylcyclopentadienone, hexaphenylbenzene, and other organic compounds. Variation in the temperature, the time, and the solvent used for the degradation reaction causes significant changes in the yields of the organic products. An investigation of the effects of adding stoichiometric amounts of free alkyne, tetra-phenylcyclopentadienone, and hexaphenylbenzene has been initiated in an attempt to understand the degradation mechanism.

Reductive coupling of carbon monoxide by U(iii) complexes—a computational study

2011 ◽  
Vol 40 (42) ◽  
pp. 11080 ◽  
Author(s):  
Georgina Aitken ◽  
Nilay Hazari ◽  
Alistair S. P. Frey ◽  
F. Geoffrey N. Cloke ◽  
O. Summerscales ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Computational Study ◽  
Reductive Coupling
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