Oxidation of olefins by palladium(II). VII. Comparison of palladium(II) chloride with other noble metal salts in the copper(II) chloride promoted oxidation in acetic acid

1974 ◽  
Vol 39 (26) ◽  
pp. 3871-3874 ◽  
Author(s):  
Patrick M. Henry
2019 ◽  
Vol 2 (1) ◽  
Author(s):  
Chengyu Jin ◽  
Lei Ma ◽  
Wenjing Sun ◽  
Peiwei Han ◽  
Xiangdong Tan ◽  
...  

AbstractSingle-atom confined materials (SACMs) have been widely researched as catalysts in many fields within recent years. However, this class of materials may not only serve as a catalyst but also as a support material for certain reactions. Here we propose a general strategy to use SACMs as supports for tuning loaded noble metal (e.g., Ru) nanoparticles with enhanced catalytic activity. As a proof of concept, a nickel single-atom confined nitrogen-doped carbon nanotube (NCNT) superstructure is prepared as a support to load noble metal Ru for catalytic wet air oxidation of acetic acid. Improved catalytic activity with a mineralization rate of ~97.5% is achieved. Further, adsorption configurations based on DFT calculations also confirm our deduction that the introduction of single-atom Ni changes the intrinsic property of NCNTs and affects the loaded active Ru nanoparticles.


2017 ◽  
Vol 7 (20) ◽  
pp. 4818-4822 ◽  
Author(s):  
Youming Ni ◽  
Lei Shi ◽  
Hongchao Liu ◽  
Wenna Zhang ◽  
Yong Liu ◽  
...  

Halide-free and noble metal-free pyridine-modified H-mordenites exhibit high stability and selectivity in methanol carbonylation to acetic acid.


1998 ◽  
Vol 177 (2) ◽  
pp. 378-385 ◽  
Author(s):  
J BARBIERJR ◽  
F DELANOE ◽  
F JABOUILLE ◽  
D DUPREZ ◽  
G BLANCHARD ◽  
...  

2013 ◽  
Vol 2 (4) ◽  
pp. 286-289
Author(s):  
Jimin Zeng ◽  
Ming Zhao ◽  
Junyu Liang ◽  
Xing Chen ◽  
Huiyan Zhang ◽  
...  

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