Kinetics of bromination of some substituted pyridinium ions by hypobromous acid in aqueous perchloric acid

1974 ◽  
Vol 39 (24) ◽  
pp. 3481-3486 ◽  
Author(s):  
Helmuth M. Gilow ◽  
John H. Ridd
Keyword(s):  
Perchloric Acid ◽  
Hypobromous Acid ◽  
Aqueous Perchloric Acid ◽  
Kinetics Of ◽  
Pyridinium Ions

Kinetics of the oxidation of iron(II) by cerium(IV) in aqueous perchloric acid

1965 ◽  
Vol 61 ◽  
pp. 689 ◽  
Author(s):  
M. G. Adamson ◽  
F. S. Dainton ◽  
P. Glentworth
Keyword(s):  
Perchloric Acid ◽  
Aqueous Perchloric Acid ◽  
Kinetics Of

ISOTOPIC EXCHANGE REACTIONS IN THE SYSTEM BROMINE – BROMATE – HYPOBROMOUS ACID

1951 ◽  
Vol 29 (8) ◽  
pp. 655-665 ◽  
Author(s):  
R. H. Betts ◽  
Agnes N. Mackenzie
Keyword(s):  
Acid Solution ◽  
Perchloric Acid ◽  
Isotopic Exchange ◽  
Exchange Reactions ◽  
Perchloric Acid Solution ◽  
Hypobromous Acid ◽  
Measurable Rate ◽  
Time Required ◽  
Secondary Chemical ◽  
Kinetics Of

Radiotracer studies with Br82 show that bromine and bromate ion in perchloric acid solution undergo isotopic exchange at a measurable rate. The kinetics of the process suggest that secondary chemical reactions occur, leading to the formation of significant concentrations of hypobromous acid in the system. The isotopic exchange between hypobromous acid and bromine is complete within the time required to separate these species.

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