Thallium in organic synthesis. XLI. Synthesis of 1-substituted 2(1H)-pyridones. New synthesis of unsymmetrical biphenyls via photochemical nitrogen-oxygen bond cleavage of 1-aroyloxy-2(1H)-pyridones

1976 ◽  
Vol 41 (1) ◽  
pp. 24-27 ◽  
Author(s):  
Edward C. Taylor ◽  
Henry W. Altland ◽  
Frank. Kienzle ◽  
Alexander. McKillop
Keyword(s):  
Organic Synthesis ◽  
Bond Cleavage ◽  
New Synthesis ◽  
Oxygen Bond

Oxygen-Oxygen Bond Cleavage and Formation in Co(II) Mediated Stoichiometric O2 Reduction via the Potential Intermediacy of a Co(IV) Oxyl Radical

2018 ◽  
Author(s):  
Lucie Nurdin ◽  
Denis M. Spasyuk ◽  
Laura Fairburn ◽  
Warren Piers ◽  
Laurent Maron
Keyword(s):  
Bond Cleavage ◽  
Peroxo Complex ◽  
Oxygen Oxygen ◽  
O2 Reduction ◽  
Oxygen Bond ◽  
Pentadentate Ligand

Diprotonation of a remarkably stable, toluene soluble cobalt peroxo complex supported by a neutral, dianionic pentadentate ligand leads to facile O-O bond cleavage and production of a highly reactive Co(IV) oxyl cation intermediate that dimerizes and releases O<sub>2</sub>. These processes are relevant to both O<sub>2</sub> reduction and O<sub>2</sub> evolution and the mechanism was probed in detail both experimentally and computationally.

Cyclopropyl Building Blocks for Organic Synthesis. Part 102. A Convenient New Synthesis of 3-Substituted ?-Lactams Formally Derived from 1-(Aminomethyl)cyclopropanecarboxylic Acids.

ChemInform ◽  
2005 ◽  
Vol 36 (5) ◽  
Author(s):  
Alessandra Zanobini ◽  
Martina Gensini ◽  
Joerg Magull ◽  
Denis Vidovic ◽  
Sergei I. Kozhushkov ◽  
...  
Keyword(s):  
Organic Synthesis ◽  
Building Blocks ◽  
New Synthesis

Ultrasonically dispersed potassium in organic synthesis. Water-acceleration in reductive CS bond cleavage reactions

1991 ◽  
Vol 32 (29) ◽  
pp. 3551-3554 ◽  
Author(s):  
Ta-shue Chou ◽  
Shao-Hwa Hung ◽  
Man-Li Peng ◽  
Shwu-Jiaun Lee
Keyword(s):  
Organic Synthesis ◽  
Bond Cleavage ◽  
Cleavage Reactions

scholarly journals Selective Formation of an FeIV O or an FeIII OOH Intermediate From Iron(II) and H2 O2 : Controlled Heterolytic versus Homolytic Oxygen-Oxygen Bond Cleavage by the Second Coordination Sphere

2018 ◽  
Vol 131 (3) ◽  
pp. 864-868 ◽  
Author(s):  
Khaled Cheaib ◽  
M. Qadri E. Mubarak ◽  
Katell Sénéchal-David ◽  
Christian Herrero ◽  
Régis Guillot ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
Bond Cleavage ◽  
Oxygen Oxygen ◽  
Second Coordination Sphere ◽  
Selective Formation ◽  
Oxygen Bond
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