Mechanistic studies on the photochemical reactions of isoxazoles

1976 ◽  
Vol 41 (1) ◽  
pp. 13-19 ◽  
Author(s):  
J. P. Ferris ◽  
R. W. Trimmer
Keyword(s):  
Photochemical Reactions ◽  
Mechanistic Studies

scholarly journals LED‐Illuminated NMR Spectroscopy: A Practical Tool for Mechanistic Studies of Photochemical Reactions

ChemPhotoChem ◽  
2019 ◽  
Vol 3 (10) ◽  
pp. 984-992 ◽  
Author(s):  
Yining Ji ◽  
Daniel A. DiRocco ◽  
Jonas Kind ◽  
Christina M. Thiele ◽  
Ruth M. Gschwind ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Photochemical Reactions ◽  
Mechanistic Studies ◽  
Practical Tool

Activation of Oxidation Catalysts by Solvation

1996 ◽  
Vol 454 ◽  
Author(s):  
Annette D. Eddowes ◽  
Dana Stallings ◽  
Caprice L. Hightower ◽  
Susan A. Jansen
Keyword(s):  
Photochemical Reactions ◽  
Oxidation Reactions ◽  
Mechanistic Studies ◽  
Oxidation Catalysts ◽  
Keggin Ion ◽  
Solution State ◽  
Keggin Type ◽  
Activation Of Oxidation

AbstractThe versatility of heteropolyanions implies many different uses for Keggin type catalysts. However, new roles for these catalysts must first be preceeded by further understanding of the mechanisms by which they operate. It has been observed that the solvation and/or complexation of heteropolyanions promotes or limits activity in homogeneous chemistry. For this reason the solution state and the solvation characteristics of the catalyst were studied in oxidation and photochemical reactions. Simple oxidation reactions provide a system by which the solution state of the catalyst can be studied. The catalyst used for these mechanistic studies is the Keggin ion (PMo10V2O40)−5.

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