Aluminum chloride catalyzed diene condensation. VI. Partial rate factors of 2-phenyl-, 2-chloro-, 2-trifluoromethyl-, and 2-cyanobutadienes in reactions with methyl acrylate. Differential Hammett correlation

1971 ◽  
Vol 36 (7) ◽  
pp. 924-928 ◽  
Author(s):  
Takashi Inukai ◽  
Takeshi Kojima
Keyword(s):  
Methyl Acrylate ◽  
Aluminum Chloride ◽  
Diene Condensation ◽  
Hammett Correlation ◽  
Partial Rate

scholarly journals Carbocationic polymerization of isobutylene with alkyl aluminum chloride / methyl acrylate as the initiating system

1999 ◽  
Vol 2 (2) ◽  
pp. 165-172 ◽  
Author(s):  
Wu Yixian ◽  
Wu Guanying ◽  
Sun Yufeng ◽  
Wang Yong ◽  
Wang Zheng ◽  
...  
Keyword(s):  
Methyl Acrylate ◽  
Aluminum Chloride ◽  
Carbocationic Polymerization ◽  
Chloride Methyl

Attempted novel preparation of dihydrocoumarin and coumarin; obtention of aryl acrylates and 3-chloropropionates

1987 ◽  
Vol 65 (1) ◽  
pp. 224-225 ◽  
Author(s):  
Jaswant R. Mahajan ◽  
Hugo C. Araújo
Keyword(s):  
Spectral Data ◽  
Methyl Acrylate ◽  
Aluminum Chloride ◽  
Substituted Phenols ◽  
Published Report

It has been found that, contrary to the published report, there is no noticeable reaction between phenol and methyl acrylate in the presence of aluminum chloride to produce phenyl acrylate (1) and dihydrocoumarin (2). Although products having the reported spectral data can be obtained by the reaction of phenol with acrylyl chloride, these products are actually phenyl acrylate and phenyl 3-chloropropionate (4), there being detected no dihydrocoumarin. This reaction has now been extended to several substituted phenols and some naphthols. Attempts at cyclization of phenyl acrylate, phenyl 3-chloropropionate, or their mixtures have been unsuccessful.

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