Benzyl alcohol as hydrogen donor in selective transfer hydrogenation of unsaturated steroids

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Simultaneous dehydrogenation of cyclohexanol to cyclohexanone and hydrogenation of α,β-unsaturated carbonyl compounds to corresponding α,β-unsaturated alcohols was carried out in a single pot reaction without addition of any external hydrogen donor.


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Single-atom (SA) catalysts have attracted broad attention for their distinctive catalytic properties in diverse reactions. Increasing unsaturated coordination sites of active centers is a valid and challenging approach to improve...


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Vol 48 (2) ◽  
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