Formation of .alpha.,.beta.-unsaturated Schiff bases from .beta.,.gamma.-unsaturated ketones. A change in rate-determining step in the reactions of 3-methyl-3-cyclohexenone with glycinamide and ethylenediamine

Robert H. Kayser; Ralph M. Pollack

doi:10.1021/jo00432a011

Formation of .alpha.,.beta.-unsaturated Schiff bases from .beta.,.gamma.-unsaturated ketones. A change in rate-determining step in the reactions of 3-methyl-3-cyclohexenone with glycinamide and ethylenediamine

The Journal of Organic Chemistry ◽

10.1021/jo00432a011 ◽

1977 ◽

Vol 42 (12) ◽

pp. 2088-2091 ◽

Cited By ~ 1

Author(s):

Robert H. Kayser ◽

Ralph M. Pollack

Keyword(s):

Schiff Bases ◽

Unsaturated Ketones ◽

Rate Determining Step ◽

Alpha Beta

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Autoxidation of enamines and Schiff bases of .alpha.,.beta.-unsaturated ketones. A new synthesis of unsaturated 1,4-diones

Journal of the American Chemical Society ◽

10.1021/ja01025a086 ◽

1968 ◽

Vol 90 (23) ◽

pp. 6565-6566 ◽

Cited By ~ 31

Author(s):

Sudarshan K. Malhotra ◽

Juraj J. Hostynek ◽

Ann F. Lundin

Keyword(s):

Schiff Bases ◽

Unsaturated Ketones ◽

New Synthesis ◽

Alpha Beta

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ChemInform Abstract: FORMATION OF α,β-UNSATURATED SCHIFF BASES FROM β,Γ-UNSATURATED KETONES. A CHANGE IN RATE-DETERMINING STEP IN THE REACTIONS OF 3-METHYL-3-CYCLOHEXENONE WITH GLYCINAMIDE AND ETHYLENEDIAMINE

Chemischer Informationsdienst ◽

10.1002/chin.197741197 ◽

1977 ◽

Vol 8 (41) ◽

pp. no-no

Author(s):

R. H. KAYSER ◽

R. M. POLLACK

Keyword(s):

Schiff Bases ◽

Unsaturated Ketones ◽

Rate Determining Step

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Base-catalyzed intermolecular condensation of .alpha.,.beta.-unsaturated ketones. Condensation of benzaldehyde with 2-butanone to diketones 3,5-diphenyl-2-methyl-4-propionylcyclohexan-1-one and 4-(2-benzalpropionyl)-3,5-diphenyl-2-methylcyclohexan-1-one

The Journal of Organic Chemistry ◽

10.1021/jo01286a028 ◽

1967 ◽

Vol 32 (11) ◽

pp. 3407-3411 ◽

Cited By ~ 5

Author(s):

Arnold T. Nielsen ◽

Henry Dubin ◽

Kerry Hise

Keyword(s):

Unsaturated Ketones ◽

Alpha Beta

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Tandem conjugate addition. Aldol reactions employing 9-(phenylseleno)-9-borabicyclononane: a novel method for effecting formal aldol condensations at the .alpha.-carbon of .alpha.,.beta.-unsaturated ketones

The Journal of Organic Chemistry ◽

10.1021/jo00205a048 ◽

1985 ◽

Vol 50 (5) ◽

pp. 730-732 ◽

Cited By ~ 30

Author(s):

William R. Leonard ◽

Tom Livinghouse

Keyword(s):

Conjugate Addition ◽

Aldol Reactions ◽

Unsaturated Ketones ◽

Novel Method ◽

Alpha Beta ◽

Alpha Carbon

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Mechanism of photochemical alcohol addition to .alpha.,.beta.-unsaturated ketones

Journal of the American Chemical Society ◽

10.1021/ja00991a078 ◽

1967 ◽

Vol 89 (15) ◽

pp. 3949-3950 ◽

Cited By ~ 17

Author(s):

B. J. Ramey ◽

Pete D. Gardner

Keyword(s):

Unsaturated Ketones ◽

Alpha Beta

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Nickel-catalyzed conjugate addition of alkynyl groups to .alpha.,.beta.-unsaturated ketones

The Journal of Organic Chemistry ◽

10.1021/jo01303a024 ◽

1980 ◽

Vol 45 (15) ◽

pp. 3053-3061 ◽

Cited By ~ 81

Author(s):

Jeffrey Schwartz ◽

Denise B. Carr ◽

Robert T. Hansen ◽

Fabian M. Dayrit

Keyword(s):

Conjugate Addition ◽

Unsaturated Ketones ◽

Alpha Beta

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Acid-catalyzed and base-catalyzed hydration of .beta.-oxy-.alpha.,.beta.-unsaturated ketones

Journal of the American Chemical Society ◽

10.1021/ja00790a029 ◽

1973 ◽

Vol 95 (9) ◽

pp. 2905-2911 ◽

Cited By ~ 14

Author(s):

L. R. Fedor ◽

N. C. De ◽

S. K. Gurwara

Keyword(s):

Unsaturated Ketones ◽

Acid Catalyzed ◽

Alpha Beta

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Stereochemistry and mechanism of the reaction of LiCuMe2 with .beta.-cyclopropyl .alpha.,.beta.-unsaturated ketones

Journal of the American Chemical Society ◽

10.1021/ja00509a033 ◽

1979 ◽

Vol 101 (15) ◽

pp. 4236-4244 ◽

Cited By ~ 42

Author(s):

Charles P. Casey ◽

Mark C. Cesa

Keyword(s):

Unsaturated Ketones ◽

Alpha Beta ◽

Mechanism Of The Reaction

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Effect of .beta.-substituents on the reactions of amines with .alpha.-bromo-.alpha.,.beta.-unsaturated ketones

The Journal of Organic Chemistry ◽

10.1021/jo01282a014 ◽

1967 ◽

Vol 32 (7) ◽

pp. 2145-2148 ◽

Cited By ~ 6

Author(s):

Norman H. Cromwell ◽

Marvin C. McMaster

Keyword(s):

Unsaturated Ketones ◽

Alpha Beta

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A comparison of the reactions of [(phenylthio)(trimethylsilyl)methyl]lithium with .alpha.,.beta.-unsaturated ketones and those of other acyl anion equivalents containing sulfur

The Journal of Organic Chemistry ◽

10.1021/jo00371a014 ◽

1986 ◽

Vol 51 (21) ◽

pp. 3983-3992 ◽

Cited By ~ 43

Author(s):

David J. Ager ◽

Michael B. East

Keyword(s):

Unsaturated Ketones ◽

Acyl Anion ◽

Alpha Beta

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