A synthetic route to highly substituted ketones. Acylations of .alpha. anions of carboxylic acid salts with acid chlorides

1977 ◽  
Vol 42 (7) ◽  
pp. 1189-1194 ◽  
Author(s):  
A. Paul Krapcho ◽  
David S. Kashdan ◽  
E. G. E. Jahngen ◽  
A. J. Lovey
Keyword(s):  
Carboxylic Acid ◽  
Acid Chlorides ◽  
Synthetic Route ◽  
Acid Salts

scholarly journals Synthesis and Characterization of the Germathioacid Chloride Coordinated by an N-Heterocyclic Carbene §

Inorganics ◽  
2018 ◽  
Vol 6 (3) ◽  
pp. 76 ◽  
Author(s):  
Yasunobu Egawa ◽  
Chihiro Fukumoto ◽  
Koichiro Mikami ◽  
Nobuhiro Takeda ◽  
Masafumi Unno
Keyword(s):  
Carboxylic Acid ◽  
Density Functional ◽  
Dft Calculation ◽  
Acid Chlorides ◽  
Carboxylic Acid Chloride ◽  
Functional Theory ◽  
Nitrogen Ligands ◽  
Bond Property ◽  
Nitrogen Bonds

Carboxylic acid chlorides are useful substrates in organic chemistry. Many germanium analogues of carboxylic acid chloride have been synthesized so far. Nevertheless, all of the reported germathioacid chlorides use bidentate nitrogen ligands and contain germanium-nitrogen bonds. Our group synthesized germathioacid chloride, Ge(S)Cl{C6H3-2,6-Tip2}(Im-i-Pr2Me2), using N-heterocyclic carbene (Im-i-Pr2Me2). As a result of density functional theory (DFT) calculation, it was found that electrons are localized on sulfur, and the germanium-sulfur bond is a single bond with a slight double bond property.

Acylation of 4,6-diamino-2-mercaptopyrimidine and its salts with carboxylic acid chlorides

1980 ◽  
Vol 29 (10) ◽  
pp. 1662-1665 ◽  
Author(s):  
G. I. Podzigun ◽  
N. G. Pashkurov ◽  
V. S. Reznik ◽  
B. E. Ivanov
Keyword(s):  
Carboxylic Acid ◽  
Acid Chlorides

ChemInform Abstract: Trialkylamine-Mediated Intramolecular Acylation of Alkenes with Carboxylic Acid Chlorides

ChemInform ◽  
2010 ◽  
Vol 41 (39) ◽  
pp. no-no
Author(s):  
Jun-ichi Matsuo ◽  
Takaya Hoshikawa ◽  
Shun Sasaki ◽  
Hiroyuki Ishibashi
Keyword(s):  
Carboxylic Acid ◽  
Acid Chlorides

ChemInform Abstract: REACTION OF TETRAALKYL METHYLENEDIPHOSPHONITES WITH CARBOXYLIC ACID CHLORIDES

1979 ◽  
Vol 10 (35) ◽  
Author(s):  
Z. S. NOVIKOVA ◽  
A. A. PRISHCHENKO ◽  
I. F. LUTSENKO
Keyword(s):  
Carboxylic Acid ◽  
Acid Chlorides
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