Synthesis of .alpha.,.beta.-unsaturated carbonyl compounds by palladium(II)-catalyzed dehydrosilylation of silyl enol ethers

Yoshihiko Ito; Toshikazu Hirao; Takeo Saegusa

doi:10.1021/jo00399a052

Synthesis of .alpha.,.beta.-unsaturated carbonyl compounds by palladium(II)-catalyzed dehydrosilylation of silyl enol ethers

The Journal of Organic Chemistry ◽

10.1021/jo00399a052 ◽

1978 ◽

Vol 43 (5) ◽

pp. 1011-1013 ◽

Cited By ~ 639

Author(s):

Yoshihiko Ito ◽

Toshikazu Hirao ◽

Takeo Saegusa

Keyword(s):

Carbonyl Compounds ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Alpha Beta

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Reaction of silyl enol ethers with β-halogenoalkyl aryl sulfides - a method of β-arylthioalkylation of carbonyl compounds

Tetrahedron Letters ◽

10.1016/s0040-4039(00)81577-4 ◽

1983 ◽

Vol 24 (9) ◽

pp. 961-964 ◽

Cited By ~ 23

Author(s):

M.A. Ibragimov ◽

W.A. Smit

Keyword(s):

Carbonyl Compounds ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Aryl Sulfides

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ChemInform Abstract: Indium-Trichloride Catalyzed Michael Reaction of Silyl Enol Ethers with α,β-Unsaturated Carbonyl Compounds under Neat Condition.

ChemInform ◽

10.1002/chin.199841036 ◽

2010 ◽

Vol 29 (41) ◽

pp. no-no

Author(s):

T.-P. LOH ◽

L.-L. WEI

Keyword(s):

Carbonyl Compounds ◽

Michael Reaction ◽

Enol Ethers ◽

Silyl Enol Ethers

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Two-step synthesis of (.gamma.,.gamma.-difluoroallyl)carbonyl compounds via addition of 1,1,2-trichloro-2,2-difluoroethyl radical to silyl enol ethers followed by reductive dechlorination

The Journal of Organic Chemistry ◽

10.1021/jo00071a027 ◽

1993 ◽

Vol 58 (19) ◽

pp. 5163-5166 ◽

Cited By ~ 25

Author(s):

Takashi Okano ◽

Toshihiro Shimizu ◽

Koji Sumida ◽

Shoji Eguchi

Keyword(s):

Reductive Dechlorination ◽

Carbonyl Compounds ◽

Enol Ethers ◽

Silyl Enol Ethers

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ChemInform Abstract: Mechanistic Studies on α-Trifluoromethylation of Ketones via Silyl Enol Ethers and Its Application to Other Carbonyl Compounds.

ChemInform ◽

10.1002/chin.200940041 ◽

2009 ◽

Vol 40 (40) ◽

Author(s):

Kazuyuki Sato ◽

Takashi Yuki ◽

Ryoji Yamaguchi ◽

Tetsuya Hamano ◽

Atsushi Tarui ◽

...

Keyword(s):

Carbonyl Compounds ◽

Mechanistic Studies ◽

Enol Ethers ◽

Silyl Enol Ethers

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ChemInform Abstract: Generation of F-Alkyl-Substituted Vinyl Thionium Ion Intermediates and Their Reaction with Silyl Enol Ethers. A New Route to δ-F-Alkyl-α,β;γ,δ-Unsaturated Carbonyl Compounds.

ChemInform ◽

10.1002/chin.199013158 ◽

1990 ◽

Vol 21 (13) ◽

Author(s):

T. ISHIHARA ◽

T. SHINOZAKI ◽

M. KUROBOSHI

Keyword(s):

Carbonyl Compounds ◽

Enol Ethers ◽

Silyl Enol Ethers

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ChemInform Abstract: REACTION OF SILYL ENOL ETHERS WITH β-HALOALKYL ARYL SULFIDES. A METHOD OF β-ARYLTHIOALKYLATION OF CARBONYL COMPOUNDS

Chemischer Informationsdienst ◽

10.1002/chin.198324182 ◽

1983 ◽

Vol 14 (24) ◽

Author(s):

M. A. IBRAGIMOV ◽

W. A. SMIT

Keyword(s):

Carbonyl Compounds ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Aryl Sulfides

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ChemInform Abstract: NEW CROSS ALDOL REACTIONS. TITANIUM TETRACHLORIDE-PROMOTED REACTIONS OF SILYL ENOL ETHERS WITH CARBONYL COMPOUNDS CONTAINING A FUNCTIONAL GROUP

Chemischer Informationsdienst ◽

10.1002/chin.197648143 ◽

1976 ◽

Vol 7 (48) ◽

pp. no-no

Author(s):

K. BANNO

Keyword(s):

Carbonyl Compounds ◽

Titanium Tetrachloride ◽

Functional Group ◽

Aldol Reactions ◽

Enol Ethers ◽

Silyl Enol Ethers

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ChemInform Abstract: Ruthenium(II)-Catalyzed Trifluorochloropropylidenation of Silyl Enol Ethers. A Facile Method for the Preparation of Trifluoromethyl-Containing Carbonyl Compounds.

ChemInform ◽

10.1002/chin.199050133 ◽

1990 ◽

Vol 21 (50) ◽

Author(s):

T. OKANO ◽

T. UEKAWA ◽

H. SAWAKI ◽

S. EGUCHI

Keyword(s):

Carbonyl Compounds ◽

Enol Ethers ◽

Silyl Enol Ethers

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Generation ofF-Alkyl-substituted Vinyl Thionium Ion Intermediates and Their Reaction with Silyl Enol Ethers. A New Route to δ-F-Alkyl-α,β;γ,δ-unsaturated Carbonyl Compounds

Chemistry Letters ◽

10.1246/cl.1989.1369 ◽

1989 ◽

Vol 18 (8) ◽

pp. 1369-1372 ◽

Cited By ~ 5

Author(s):

Takashi Ishihara ◽

Takao Shinozaki ◽

Manabu Kuroboshi

Keyword(s):

Carbonyl Compounds ◽

Enol Ethers ◽

Silyl Enol Ethers

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The Copper(I) Chloride-Catalyzed Reaction of Ketene Silyl Acetals or Silyl Enol Ethers with α-Halogen Substituted Allylsilanes to Form Carbonyl Compounds Bearing Vinylsilane Functionality

Letters in Organic Chemistry ◽

10.2174/157017807780737273 ◽

2007 ◽

Vol 4 (3) ◽

pp. 181-184 ◽

Cited By ~ 1

Author(s):

Michiharu Mitani ◽

Masayuki Masuda

Keyword(s):

Carbonyl Compounds ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Silyl Acetals

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