Fast and selective oxidation of primary alcohols to aldehydes or to carboxylic acids and of secondary alcohols to ketones mediated by oxoammonium salts under two-phase conditions

1987 ◽  
Vol 52 (12) ◽  
pp. 2559-2562 ◽  
Author(s):  
Pier Lucio Anelli ◽  
Carlo Biffi ◽  
Fernando Montanari ◽  
Silvio Quici
Keyword(s):  
Carboxylic Acids ◽  
Selective Oxidation ◽  
Secondary Alcohols ◽  
Primary Alcohols ◽  
Two Phase ◽  
Oxoammonium Salts

Studies on transition-metal nitrido and oxo complexes. Part 20. Oxoruthenates and oxo-osmates in oxidation catalysis; cis-[Os(OH)2O4]2- as a catalytic oxidant for primary amines and for alcohols

2001 ◽  
Vol 79 (5-6) ◽  
pp. 598-606 ◽  
Author(s):  
William P Griffith ◽  
Maria Suriaatmaja
Keyword(s):  
Raman Spectroscopy ◽  
Transition Metal ◽  
Carboxylic Acids ◽  
Oxidative Dehydrogenation ◽  
Alcohol Oxidation ◽  
Oxidation Catalysis ◽  
Primary Amines ◽  
Secondary Alcohols ◽  
Primary Alcohols ◽  
Aromatic And Aliphatic Amines

cis-[Os(OH)2O4]2– with [Fe(CN)6]3– and other co-oxidants has been studied as a catalytic reagent for the oxidative dehydrogenation of primary aromatic and aliphatic amines to nitriles, the oxidation of primary alcohols to carboxylic acids and of secondary alcohols to ketones. Electronic and Raman spectroscopy have been used to elucidate the nature of the oxoruthenates and oxo-osmates present in a number of reported organic oxidations catalyzed by ruthenium and osmium species.Key words: oxidation catalysis, ruthenium, osmium, amine dehydrogenation, alcohol oxidation.

scholarly journals Biocatalytic Oxidation of Alcohols

Catalysts ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 952 ◽  
Author(s):  
Hendrik Puetz ◽  
Eva Puchľová ◽  
Kvetoslava Vranková ◽  
Frank Hollmann
Keyword(s):  
Selective Oxidation ◽  
State Of The Art ◽  
Secondary Alcohols ◽  
Primary Alcohols ◽  
Enantioselective Oxidation ◽  
Current State ◽  
Oxidation Of Alcohols ◽  
Enzymatic Methods

Enzymatic methods for the oxidation of alcohols are critically reviewed. Dehydrogenases and oxidases are the most prominent biocatalysts, enabling the selective oxidation of primary alcohols into aldehydes or acids. In the case of secondary alcohols, region and/or enantioselective oxidation is possible. In this contribution, we outline the current state-of-the-art and discuss current limitations and promising solutions.

Efficient and Highly Selective Oxidation of Primary Alcohols to Aldehydes byN-Chlorosuccinimide Mediated by Oxoammonium Salts

1996 ◽  
Vol 61 (21) ◽  
pp. 7452-7454 ◽  
Author(s):  
Jacques Einhorn ◽  
Cathy Einhorn ◽  
Fabien Ratajczak ◽  
Jean-Louis Pierre
Keyword(s):  
Selective Oxidation ◽  
Primary Alcohols ◽  
Oxoammonium Salts

scholarly journals A green and sustainable phosphine-free NHC-ruthenium catalyst for selective oxidation of alcohols to carboxylic acids in water

2015 ◽  
Vol 44 (39) ◽  
pp. 17409-17414 ◽  
Author(s):  
Jagadeesh Malineni ◽  
Helmut Keul ◽  
Martin Möller
Keyword(s):  
Oxygen Atom ◽  
Carboxylic Acids ◽  
Selective Oxidation ◽  
Direct Synthesis ◽  
Ruthenium Catalyst ◽  
Catalytic Dehydrogenation ◽  
Oxidizing Agent ◽  
Primary Alcohols ◽  
Oxidation Of Alcohols ◽  
Atom Source

An efficient novel protocol is applied for direct synthesis of carboxylic acids from primary alcohols through catalytic dehydrogenation. This reaction occurs in water as the solvent and as the oxygen-atom source and no toxic oxidizing agent is involved.

Sign in / Sign up

Export Citation Format

Share Document