Reaction of arylmethanes and heteroarylmethanes with the tert-butoxy radical

1987 ◽  
Vol 52 (8) ◽  
pp. 1555-1559 ◽  
Author(s):  
Belaid Mahiou ◽  
Gerald Jay Gleicher
Keyword(s):  
Butoxy Radical

Identification of an unexpected peroxide formed by successive isomerization reactions of the n-butoxy radical in oxygen

1996 ◽  
Vol 92 (21) ◽  
pp. 4167 ◽  
Author(s):  
Fran�ois Jorand ◽  
Adolphe Heiss ◽  
Krikor Sahetchian ◽  
Lucien Kerhoas ◽  
Jacques Einhorn
Keyword(s):  
Butoxy Radical

On the Unimolecular Decomposition of the tert-Butoxy Radical

1973 ◽  
Vol 51 (13) ◽  
pp. 2138-2140 ◽  
Author(s):  
C. K. Yip ◽  
H. O. Pritchard
Keyword(s):  
Pressure Dependence ◽  
Unimolecular Reaction ◽  
Unimolecular Decomposition ◽  
Reaction Theory ◽  
Butoxy Radical

It is argued that a large apparent pressure dependence in the rate of decomposition of the tert-butoxy radical should not be interpreted in terms of unimolecular reaction theory; the effect is probably heterogeneous in origin.

Arrhenius parameters for the tert-butoxy radical reactions with trimethylsilane in the gas phase

1982 ◽  
Vol 104 (23) ◽  
pp. 6445-6448 ◽  
Author(s):  
Chan Ryang Park ◽  
Se Ahn Song ◽  
Yong Eun Lee ◽  
Kwang Yul Choo
Keyword(s):  
Gas Phase ◽  
Radical Reactions ◽  
Arrhenius Parameters ◽  
Butoxy Radical

Photolysis of Di-tert-butyl Peroxide at High Pressure

1972 ◽  
Vol 50 (10) ◽  
pp. 1531-1534 ◽  
Author(s):  
C. K. Yip ◽  
H. O. Pritchard
Keyword(s):  
Thermal Decomposition ◽  
High Pressure ◽  
Gaseous Phase ◽  
Chemical Reactivity ◽  
Hydrocarbon Concentration ◽  
Tert Butyl ◽  
Butyl Peroxide ◽  
Butoxy Radical ◽  
Peroxide Molecule

Di-tert-butyl peroxide has been photolyzed at 2537 Å in the gaseous phase in the presence of up to 47 amagats (2.10 mol/l) of propane and of cyclopropane. It was confirmed that no acetone is formed in the limit of infinite hydrocarbon concentration and therefore that the primary chemical act leading to the eventual formation of acetone is the formation of two tert-butoxy radicals from the excited peroxide molecule; in addition, some crude information was obtained concerning relative rates of photochemical vs. deactivation processes. It was also found that at these densities the tert-butoxy radical formed in the photolysis of di-tert-butyl peroxide did not appear to differ in chemical reactivity from the tert-butoxy radical formed in the thermal decomposition of di-tert-butyl peroxide.

Photodissociation of tert-butyl hypochlorite and decomposition of the tert-butoxy radical fragment

1993 ◽  
Vol 97 (23) ◽  
pp. 6220-6225 ◽  
Author(s):  
M. A. Thelen ◽  
P. Felder ◽  
J. G. Frey ◽  
J. Robert Huber
Keyword(s):  
Tert Butyl ◽  
Butoxy Radical ◽  
Radical Fragment
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