Carbon-carbon bond fragmentation through oxidative electrolysis of carboxylic acids and its application to the synthesis of malyngolide

1986 ◽  
Vol 51 (14) ◽  
pp. 2844-2847 ◽  
Author(s):  
Peter G. M. Wuts ◽  
Minn Chang Cheng
Keyword(s):  
Carboxylic Acids ◽  
Carbon Bond ◽  
Carbon Carbon Bond

Deoxygenative Transformation of Carbonyl and Carboxyl Compounds Using gem-Diborylalkanes

Synlett ◽  
2019 ◽  
Vol 30 (10) ◽  
pp. 1105-1110 ◽  
Author(s):  
Yue Hu ◽  
Wei Sun ◽  
Chao Liu
Keyword(s):  
Carboxylic Acid ◽  
Carboxylic Acids ◽  
Carbon Bond ◽  
Recent Advances ◽  
Carbon Carbon Bond ◽  
Efficient Construction

gem-Diborylalkanes serve as privileged carbanion precursors for the efficient construction of carbon–carbon bond with various carbonyl and carboxyl compounds. We highlight the recent advances on deoxygenative transformation of carbonyl and carboxyl compounds using gem-diborylalkanes reagents. Our recent development of a dual functionalization of gem-diborylalkanes through deoxygenative enolization with the carboxylic acids is also discussed.1 Introduction2 Activation Modes of gem-Diborylalkanes3 Deoxygenative Transformation of Carbonyl and Carboxyl ­Compounds via α-Diboryl Carbanion3.1 Reaction with Aldehyde and Ketone Electrophiles3.2 Reaction with Carboxylic Acid Derivatives4 Deoxygenative Transformation of Carbonyl and Carboxyl ­Compounds via α-Monoboryl Carbanion5 Conclusion

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